A comparison of various approaches used in source apportionments for precipitation nitrogen in a mountain region of southwest China
Cui, Jian1; Zhou, Fengwu1; Gao, Min1; Zhang, Liuyi1; Zhang, Leiming2; Du, Ke3; Leng, Qiangmei1; Zhang, Yuanzhu4; He, Dongyi1; Yang, Fumo1,5
刊名ENVIRONMENTAL POLLUTION
2018-10-01
卷号241页码:810-820
关键词Source Apportionment Method Inter-comparison Precipitation Nitrogen Delta N-15 Signature
ISSN号0269-7491
DOI10.1016/j.envpol.2018.06.028
英文摘要

Six different approaches are applied in the present study to apportion the sources of precipitation nitrogen making use of precipitation data of dissolved inorganic nitrogen (DIN, including NO3- and NH4+), dissolved organic nitrogen (DON) and delta N-15 signatures of DIN collected at six sampling sites in the mountain region of Southwest China. These approaches include one quantitative approach running a Bayesian isotope mixing model (SIAR model) and five qualitative approaches based on in-situ survey (ISS), ratio of NH4+/NO3- (R-N), principal component analysis (PCA), canonical-correlation analysis (CCA) and stable isotope approach (SIA). Biomass burning, coal combustion and mobile exhausts in the mountain region are identified as major sources for precipitation DIN while biomass burning and volatilization sources such as animal husbandries are major ones for DON. SIAR model results suggest that mobile exhausts, biomass burning and coal combustion contributed 25.1 +/- 14.0%, 26.0 +/- 14.1% and 27.0 +/- 12.6%, respectively, to NO3- on the regional scale. Higher contributions of both biomass burning and coal combustion appeared at rural and urban sites with a significant difference between Houba (rural) and the wetland site (p < 0.05). The R-N method fails to properly identify sources of DIN, the ISS and SIA approach only respectively identifies DON and DIN sources, the PCA only tracks source types for precipitation N, while the CCA identify sources of both DIN and DON in precipitation. SIAR quantified the contributions of major sources to precipitation NO3- but failed for precipitation NH4+ and DON. It is recommended to use ISS and SIAR in combination with one or more approaches from PCA, CCA and SIA to apportion precipitation NO3+ sources. As for apportioning precipitation NH4- sources, more knowledge is needed for local N-15 databases of NH3 and DON and N-15 fractional mechanisms among gaseous, liquid and particulate surfaces in this mountain region and similar environments. (C) 2018 Elsevier Ltd. All rights reserved.

资助项目National Natural Science Foundation of China[41571461] ; Program of Chongqing Science & Technology Commission[cstc2015jcyjBX0025] ; Collaborative Innovation Program for Joint Scholars of Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences[R53A500Z10] ; West Action Plan of the Chinese Academy of Science[KZCX2-XB3-14] ; Key Laboratory of Reservoir Aquatic Environment of CAS[0973606]
WOS研究方向Environmental Sciences & Ecology
语种英语
出版者ELSEVIER SCI LTD
WOS记录号WOS:000440390800085
内容类型期刊论文
源URL[http://119.78.100.138/handle/2HOD01W0/6558]  
专题大气环境研究中心
作者单位1.Chinese Acad Sci, Chongqing Inst Green & Intelligent Technol, Ctr Atmospher Environm Res, Chongqing 400714, Peoples R China
2.Environm & Climate Change Canada, Air Qual Res Div, Sci & Technol Branch, Toronto, ON M3H 5T4, Canada
3.Univ Calgary, Dept Mech & Mfg Engn, Calgary, AB T2N 1N4, Canada
4.Southwest Univ, Sch Geog Sci, Chongqing Key Lab Karst Environm, Chongqing, Peoples R China
5.Chinese Acad Sci, Inst Urban Environm, Ctr Excellence Reg Atmospher Environm, Xiamen 361021, Peoples R China
6.Univ Nottingham, Fac Engn, Malaysia Campus,Jalan Broga, Semenyih 43500, Selangor Darul, Malaysia
推荐引用方式
GB/T 7714
Cui, Jian,Zhou, Fengwu,Gao, Min,et al. A comparison of various approaches used in source apportionments for precipitation nitrogen in a mountain region of southwest China[J]. ENVIRONMENTAL POLLUTION,2018,241:810-820.
APA Cui, Jian.,Zhou, Fengwu.,Gao, Min.,Zhang, Liuyi.,Zhang, Leiming.,...&Chan, Andy.(2018).A comparison of various approaches used in source apportionments for precipitation nitrogen in a mountain region of southwest China.ENVIRONMENTAL POLLUTION,241,810-820.
MLA Cui, Jian,et al."A comparison of various approaches used in source apportionments for precipitation nitrogen in a mountain region of southwest China".ENVIRONMENTAL POLLUTION 241(2018):810-820.
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