Formation of nickel-doped magnetite hollow nanospheres with high specific surface area and superior removal capability for organic molecules
Li, Zhenhu1,2; Ma, Yurong1; Qi, Limin1
刊名NANOTECHNOLOGY
2016-12-02
卷号27期号:48页码:11
关键词hollow nanospheres NixFe3-xO4 adsorption capacity solvothermal method
ISSN号0957-4484
DOI10.1088/0957-4484/27/48/485601
通讯作者Ma, YR (reprint author), Peking Univ, Coll Chem, Beijing Natl Lab Mol Sci, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100871, Peoples R China.
英文摘要A strategy for the formation of magnetic NixFe3-xO4 hollow nanospheres with very high specific surface areas was designed through a facile solvothermal method in mixed solvents of ethylene glycol and water in this work. The Ni/Fe ratios and the crystal phases of the NixFe(3-x)O(4) hollow nanocrystals can be readily tuned by changing the molar ratios of Ni to Fe in the precursors. An inside-out Ostwald ripening mechanism was proposed for the formation of uniform NixFe(3-x)O(4) hollow nanospheres. Moreover, the obtained NixFe(3-x)O(4) hollow nanospheres exhibited excellent adsorption capacity towards organic molecules such as Congo red in water. The maximum adsorption capacities of NixFe(3-x)O(4) hollow nanospheres for Congo red increase dramatically from 263 to 500 mg g(-1) with the increase of the Ni contents (x) in NixFe(3-x)O(4) hollow nanospheres from 0.2 to 0.85. The synthesized NixFe(3-x)O(4) nanoparticles can be potentially applied for waste water treatment.
资助项目National Natural Science Foundation of China[51272298] ; National Natural Science Foundation of China[21473004]
WOS研究方向Science & Technology - Other Topics ; Materials Science ; Physics
语种英语
出版者IOP PUBLISHING LTD
WOS记录号WOS:000387685500001
内容类型期刊论文
源URL[http://119.78.100.138/handle/2HOD01W0/426]  
专题微纳制造与系统集成研究中心
通讯作者Ma, Yurong
作者单位1.Peking Univ, Coll Chem, Beijing Natl Lab Mol Sci, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100871, Peoples R China
2.Chinese Acad Sci, Chongqing Inst Green & Intelligent Technol, Chongqing Key Lab Multiscale Mfg Technol, Chongqing 400714, Peoples R China
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Li, Zhenhu,Ma, Yurong,Qi, Limin. Formation of nickel-doped magnetite hollow nanospheres with high specific surface area and superior removal capability for organic molecules[J]. NANOTECHNOLOGY,2016,27(48):11.
APA Li, Zhenhu,Ma, Yurong,&Qi, Limin.(2016).Formation of nickel-doped magnetite hollow nanospheres with high specific surface area and superior removal capability for organic molecules.NANOTECHNOLOGY,27(48),11.
MLA Li, Zhenhu,et al."Formation of nickel-doped magnetite hollow nanospheres with high specific surface area and superior removal capability for organic molecules".NANOTECHNOLOGY 27.48(2016):11.
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