Highly Sensitive SERS Detection of As(3+) Ions in Aqueous Media using Glutathione Functionalized Silver Nanoparticles | |
Li, JL ; Chen, LX ; Lou, TT ; Wang, YQ | |
刊名 | ACS APPLIED MATERIALS & INTERFACES |
2011 | |
卷号 | 3期号:10页码:3936-3941 |
关键词 | Arsenic Ion Surface-enhanced Raman Scattering Silver Nanoparticles Glutathione 4-mercaptopyridine Enhanced Raman-scattering Atomic Fluorescence Spectrometry Arsenic Speciation Gold Nanoparticles Spectroscopy Identification Environment Technology System |
ISSN号 | 1944-8244 |
通讯作者 | Chen, LX (reprint author), Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Zone Environm Proc, Yantai 264003, Peoples R China |
产权排序 | [Li, Jinglian; Chen, Lingxin; Lou, Tingting; Wang, Yunqing] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Zone Environm Proc, Yantai 264003, Peoples R China; [Li, Jinglian; Lou, Tingting] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
英文摘要 | A highly sensitive surface-enhanced Raman scattering (SERS) platform for the selective trace analysis of As(3+) ions was reported based on glutathione (GSH)/4-mercaptopyridine (4-MPY)-modified silver nanoparticles (AgNPs). Here, GSH conjugated on the surface of AgNPs for specifical binding with As(3+) ions in aqueous solution through As-O linkage and 4-MPY was used as a Raman reporter. When As(3+) ions were added to the system, the binding of As(3+) with GSH resulted in the aggregation of AgNPs, and excellent Raman signal of 4-MPY reporters was obtained which can reflect the concentration of As(3+) indirectly. Under optimal assay conditions, the limit of detection (LOD) was estimated to be as low as 0.76 ppb, which is lower than the WHO defined limit (10 ppb), and an excellent linear range of 4-300 ppb was obtained. The practical application had been carried out for determination of As(3+) in real water samples. |
学科主题 | Science & Technology - Other Topics ; Materials Science |
URL标识 | 查看原文 |
语种 | 英语 |
公开日期 | 2012-03-06 |
内容类型 | 期刊论文 |
源URL | [http://ir.yic.ac.cn/handle/133337/5339] |
专题 | 烟台海岸带研究所_山东省海岸带环境工程技术研究中心 烟台海岸带研究所_海岸带生物学与生物资源利用所重点实验室 烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室 |
推荐引用方式 GB/T 7714 | Li, JL,Chen, LX,Lou, TT,et al. Highly Sensitive SERS Detection of As(3+) Ions in Aqueous Media using Glutathione Functionalized Silver Nanoparticles[J]. ACS APPLIED MATERIALS & INTERFACES,2011,3(10):3936-3941. |
APA | Li, JL,Chen, LX,Lou, TT,&Wang, YQ.(2011).Highly Sensitive SERS Detection of As(3+) Ions in Aqueous Media using Glutathione Functionalized Silver Nanoparticles.ACS APPLIED MATERIALS & INTERFACES,3(10),3936-3941. |
MLA | Li, JL,et al."Highly Sensitive SERS Detection of As(3+) Ions in Aqueous Media using Glutathione Functionalized Silver Nanoparticles".ACS APPLIED MATERIALS & INTERFACES 3.10(2011):3936-3941. |
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