Determination of 16 polycyclic aromatic hydrocarbons in environmental water samples by solid-phase extraction using multi-walled carbon nanotubes as adsorbent coupled with gas chromatography-mass spectrometry

CORC > 烟台海岸带研究所 > 中国科学院烟台海岸带研究所 > 山东省海岸带环境工程技术研究中心

	Determination of 16 polycyclic aromatic hydrocarbons in environmental water samples by solid-phase extraction using multi-walled carbon nanotubes as adsorbent coupled with gas chromatography-mass spectrometry
	Ma, Jiping 1; Xiao, Ronghui 1; Li, Jinhua2 ; Yu, Junbao2 ; Zhang, Yanqing 1; Chen, Lingxin2
刊名	JOURNAL OF CHROMATOGRAPHY A
	2010-08-20
卷号	1217 期号:34 页码:5462-5469
关键词	Polycyclic Aromatic Hydrocarbons (Pahs) Solid-phase Extraction (Spe) Multi-walled Carbon Nanotubes (Mwcnts) Gas Chromatography-mass Spectrometry (Gc-ms) Water Samples
ISSN号	0021-9673
通讯作者	Ma, JP, Qingdao Technol Univ, Inst Environm & Municipal Engn, Key Lab Environm Engn Shandong Prov, Qingdao 266033, Peoples R China
产权排序	[Ma, Jiping; Xiao, Ronghui; Zhang, Yanqing] Qingdao Technol Univ, Inst Environm & Municipal Engn, Key Lab Environm Engn Shandong Prov, Qingdao 266033, Peoples R China; [Li, Jinhua; Yu, Junbao; Chen, Lingxin] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc, Yantai 264003, Peoples R China
文献子类	Article
英文摘要	A solid-phase extraction (SPE) using multi-walled carbon nanotubes (MWCNTs) as adsorbent coupled with gas chromatography-mass spectrometry (GC-MS) method was developed for the determination of 16 polycyclic aromatic hydrocarbons (PAHs) in environmental water samples. Several condition parameters, such as extraction adsorbents, elution solvents and volumes, and sample loading flow rate and volume were optimized to obtain high SPE recoveries and extraction efficiency. 150 mg MWCNTs as sorbent presented high extraction efficiency of 16 PAHs due to the large specific surface area and high adsorption capacity of MWCNTs compared with the commercial C18 column (250 mg/2 mL). The calibration curves of 16 PAHs extracted were linear in the range of 20-5000 ng L-1, with the correlation coefficients (r(2)) between 0.9848 and 0.9991. The method attained good precisions (relative standard deviation, RSD) from 1.2% to 12.1% for standard PAHs aqueous solutions; method recoveries ranged in 76.0-125.5%, 74.5-127.0%, and 70.0-122.0% for real spiked samples from river water, tap water and seawater, respectively. Limits of detection (LODs, S/N = 3) of the method were determined from 2.0 to 8.5 ng L-1. The optimized method was successfully applied to the determination of 16 PAHs in real environmental water samples. (C) 2010 Elsevier B.V. All rights reserved.; A solid-phase extraction (SPE) using multi-walled carbon nanotubes (MWCNTs) as adsorbent coupled with gas chromatography-mass spectrometry (GC-MS) method was developed for the determination of 16 polycyclic aromatic hydrocarbons (PAHs) in environmental water samples. Several condition parameters, such as extraction adsorbents, elution solvents and volumes, and sample loading flow rate and volume were optimized to obtain high SPE recoveries and extraction efficiency. 150 mg MWCNTs as sorbent presented high extraction efficiency of 16 PAHs due to the large specific surface area and high adsorption capacity of MWCNTs compared with the commercial C18 column (250 mg/2 mL). The calibration curves of 16 PAHs extracted were linear in the range of 20-5000 ng L(-1), with the correlation coefficients (r(2)) between 0.9848 and 0.9991. The method attained good precisions (relative standard deviation, RSD) from 1.2% to 12.1% for standard PAHs aqueous solutions; method recoveries ranged in 76.0-125.5%, 74.5-127.0%, and 70.0-122.0% for real spiked samples from river water, tap water and seawater, respectively. Limits of detection (LODs, S/N = 3) of the method were determined from 2.0 to 8.5 ng L(-1). The optimized method was successfully applied to the determination of 16 PAHs in real environmental water samples. (C) 2010 Elsevier B.V. All rights reserved.
学科主题	Biochemical Research Methods ; Chemistry, Analytical
URL标识	查看原文
WOS关键词	PERFORMANCE LIQUID-CHROMATOGRAPHY ; BAR SORPTIVE EXTRACTION ; TREATMENT-PLANT ; MICROEXTRACTION ; PAHS ; PENTACHLOROPHENOL ; GROUNDWATER ; ORGANOCLAY ; SEDIMENTS ; MUSSELS
WOS研究方向	Biochemistry & Molecular Biology ; Chemistry
语种	英语
WOS记录号	WOS:000281291000002
资助机构	Ministry of Water Resources Public Welfare Specialized Research Foundation of China [200901063]; Education Commission Natural Science Foundation of Shandong Province [J07WZ05]; Qingdao Technological University [c2007-008]; Water Body Pollution Controlling and Treatment Significant Special Project Foundation of China Science and Technology [2009ZX07317-008-02]; Department of Science and Technology of Shandong Province of China [2008GG20005005]; CAS/SAFEA International Partnership Program for Creative Research Teams ; Chinese Academy of Sciences
公开日期	2011-07-14
内容类型	期刊论文
源URL	[http://ir.yic.ac.cn/handle/133337/3712]
专题	烟台海岸带研究所_山东省海岸带环境工程技术研究中心烟台海岸带研究所_滨海湿地实验室
作者单位	1.Qingdao Technol Univ, Inst Environm & Municipal Engn, Key Lab Environm Engn Shandong Prov, Qingdao 266033, Peoples R China 2.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc, Yantai 264003, Peoples R China
推荐引用方式 GB/T 7714	Ma, Jiping,Xiao, Ronghui,Li, Jinhua,et al. Determination of 16 polycyclic aromatic hydrocarbons in environmental water samples by solid-phase extraction using multi-walled carbon nanotubes as adsorbent coupled with gas chromatography-mass spectrometry[J]. JOURNAL OF CHROMATOGRAPHY A,2010,1217(34):5462-5469.
APA	Ma, Jiping,Xiao, Ronghui,Li, Jinhua,Yu, Junbao,Zhang, Yanqing,&Chen, Lingxin.(2010).Determination of 16 polycyclic aromatic hydrocarbons in environmental water samples by solid-phase extraction using multi-walled carbon nanotubes as adsorbent coupled with gas chromatography-mass spectrometry.JOURNAL OF CHROMATOGRAPHY A,1217(34),5462-5469.
MLA	Ma, Jiping,et al."Determination of 16 polycyclic aromatic hydrocarbons in environmental water samples by solid-phase extraction using multi-walled carbon nanotubes as adsorbent coupled with gas chromatography-mass spectrometry".JOURNAL OF CHROMATOGRAPHY A 1217.34(2010):5462-5469.