Broad spectral-response organic D-A-pi-A sensitizer with pyridine-diketopyrrolopyrrole unit for dye-sensitized solar cells

doi:10.1039/c5ra27288b

CORC > 合肥物质科学研究院 > 中国科学院合肥物质科学研究院 > 应用技术研究所

	Broad spectral-response organic D-A-pi-A sensitizer with pyridine-diketopyrrolopyrrole unit for dye-sensitized solar cells
	Guo, Fuling 1; Liu, Xuepeng 1; Ding, Yong 1; Kong, Fantai 1; Chen, Wangchao 1; Zhou, Li 1; Dai, Songyuan 1,2
刊名	RSC ADVANCES
	2016
卷号	6 期号:16 页码:13433-13441
DOI	10.1039/c5ra27288b
文献子类	Article
英文摘要	In this work, four D-A-pi-A sensitizers PDPP-I-IV based on pyridine-flanked DPP moieties (PDPP) were designed and synthesized for dye-sensitized solar cells. Remarkably, the incorporated electron-withdrawing unit of pyridine-flanked DPP improves the light-harvesting ability and modifies the electrochemical and absorption properties, generating a broader IPCE wavelength responding region. The electrochemical experiments and time-resolved photoluminescence measurements indicate the ability of electron-injection into the TiO2 conductive band from the excited sensitizer. The transient absorption spectra were measured to investigate the feasibility of the dynamics for oxidized-state sensitizer regeneration. The IPCE spectra demonstrate the broad spectral response region of these sensitizers. Especially, the IPCE of PDPP-III reached the near infrared (NIR) region (>800 nm) with the highest short-circuit current of 16.17 mA cm(-2) in these sensitizers. Furthermore, the electrochemical impedance spectroscopy (EIS) experiments suggest that the electron-lifetime and charge recombination resistance increased when attaching the stereo substituted groups (R-2) on the PDPP moiety, resulting in a higher open-circuit voltage (V-oc). It can be found that PDPP-II based DSSCs with liquid electrolyte exhibited the highest V-oc (523 mV) and power conversion efficiency (PCE) of 5.26%.
WOS关键词	HIGHLY-EFFICIENT ; PORPHYRIN SENSITIZERS ; BUILDING-BLOCK ; TIO2 FILMS ; LIGHT ; DPP ; ACCEPTOR ; DESIGN ; DONOR ; DERIVATIVES
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:000369546100081
资助机构	Natural Science Foundation of Anhui Province(1508085SMF224) ; Natural Science Foundation of Anhui Province(1508085SMF224) ; Natural Science Foundation of Anhui Province(1508085SMF224) ; Natural Science Foundation of Anhui Province(1508085SMF224) ; National High Technology Research and Development Program of China(2015AA050602) ; National High Technology Research and Development Program of China(2015AA050602) ; National High Technology Research and Development Program of China(2015AA050602) ; National High Technology Research and Development Program of China(2015AA050602) ; National Natural Science Foundation of China(21273242) ; National Natural Science Foundation of China(21273242) ; National Natural Science Foundation of China(21273242) ; National Natural Science Foundation of China(21273242) ; State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources(LAPS14012) ; State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources(LAPS14012) ; State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources(LAPS14012) ; State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources(LAPS14012) ; Natural Science Foundation of Anhui Province(1508085SMF224) ; Natural Science Foundation of Anhui Province(1508085SMF224) ; Natural Science Foundation of Anhui Province(1508085SMF224) ; Natural Science Foundation of Anhui Province(1508085SMF224) ; National High Technology Research and Development Program of China(2015AA050602) ; National High Technology Research and Development Program of China(2015AA050602) ; National High Technology Research and Development Program of China(2015AA050602) ; National High Technology Research and Development Program of China(2015AA050602) ; National Natural Science Foundation of China(21273242) ; National Natural Science Foundation of China(21273242) ; National Natural Science Foundation of China(21273242) ; National Natural Science Foundation of China(21273242) ; State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources(LAPS14012) ; State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources(LAPS14012) ; State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources(LAPS14012) ; State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources(LAPS14012)
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/22279]
专题	合肥物质科学研究院_应用技术研究所
作者单位	1.Chinese Acad Sci, Hefei Inst Phys Sci, Inst Appl Technol, Key Lab Novel Thin Film Solar Cells, Hefei 230031, Anhui, Peoples R China 2.North China Elect Power Univ, Beijing Key Lab Novel Thin Film Solar Cells, Beijing 102206, Peoples R China
推荐引用方式 GB/T 7714	Guo, Fuling,Liu, Xuepeng,Ding, Yong,et al. Broad spectral-response organic D-A-pi-A sensitizer with pyridine-diketopyrrolopyrrole unit for dye-sensitized solar cells[J]. RSC ADVANCES,2016,6(16):13433-13441.
APA	Guo, Fuling.,Liu, Xuepeng.,Ding, Yong.,Kong, Fantai.,Chen, Wangchao.,...&Dai, Songyuan.(2016).Broad spectral-response organic D-A-pi-A sensitizer with pyridine-diketopyrrolopyrrole unit for dye-sensitized solar cells.RSC ADVANCES,6(16),13433-13441.
MLA	Guo, Fuling,et al."Broad spectral-response organic D-A-pi-A sensitizer with pyridine-diketopyrrolopyrrole unit for dye-sensitized solar cells".RSC ADVANCES 6.16(2016):13433-13441.