Macroporous Inverse Opal-like MoXC with Incorporated Mo Vacancies for Significantly Enhanced Hydrogen Evolution

doi:10.1021/acsnano.7b04205

CORC > 合肥物质科学研究院 > 中国科学院合肥物质科学研究院 > 中科院固体物理研究所

	Macroporous Inverse Opal-like MoXC with Incorporated Mo Vacancies for Significantly Enhanced Hydrogen Evolution
	Li, Feng 1; Zhao, Xianglong 3; Mahmood, Jawed 1; Okyay, Mahmut Salt 2; Jung, Sun-Min 1; Ahmad, Ishfaq 1; Kim, Seok-Jin 1; Han, Gao-Feng 1; Park, Noejung 2; Baek, Jong-Beom 1
刊名	ACS NANO
	2017-07-01
卷号	11 期号:7 页码:7527-7533
关键词	Molybdenum Carbide Inverse Opal Mo Vacancies Hydrogen Evolution Binding Energy
DOI	10.1021/acsnano.7b04205
文献子类	Article
英文摘要	The hydrogen evolution reaction (HER) is one of the most important pathways for producing pure and clean hydrogen. Although platinum (Pt) is the most efficient HER electrocatalyst, its practical application is significantly hindered by high cost and scarcity. In this work, an MoxS with incorporated Mo vacancies and macroporous inverse opal-like (IOL) structure (MoxC-IOL) was synthesized and studied as a low-cost efficient HER electrocatalyst. The macroporous IOL structure was controllably fabricated using a facile-hard template strategy. As a result of the combined benefits of the Mo vacancies and structural advantages, including appropriate hydrogen binding energy, large exposed surface, robust IOL structure and fast mass/charge transport, the synthesized MoxC-IOL exhibited significantly enhanced HER electrocatalytic performance with good stability, with performance comparable or superior to Pt wire in both acidic and alkaline solutions.
WOS关键词	ACTIVE EDGE SITES ; TOTAL-ENERGY CALCULATIONS ; WAVE BASIS-SET ; ELECTROLYTIC HYDROGEN ; ULTRATHIN NANOSHEETS ; ORIENTED ATTACHMENT ; CATALYTIC-ACTIVITY ; EFFICIENT ; ELECTROCATALYSIS ; DEFECTS
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science
语种	英语
WOS记录号	WOS:000406649700103
资助机构	Creative Research Initiative (CRI) program through the National Research Foundation (NRF) of Korea(2014R1A2069102) ; Creative Research Initiative (CRI) program through the National Research Foundation (NRF) of Korea(2014R1A2069102) ; Creative Research Initiative (CRI) program through the National Research Foundation (NRF) of Korea(2014R1A2069102) ; Creative Research Initiative (CRI) program through the National Research Foundation (NRF) of Korea(2014R1A2069102) ; Creative Research Initiative (CRI) program through the National Research Foundation (NRF) of Korea(2014R1A2069102) ; Creative Research Initiative (CRI) program through the National Research Foundation (NRF) of Korea(2014R1A2069102) ; Creative Research Initiative (CRI) program through the National Research Foundation (NRF) of Korea(2014R1A2069102) ; Creative Research Initiative (CRI) program through the National Research Foundation (NRF) of Korea(2014R1A2069102) ; Science Research Center (SRC) program through the National Research Foundation (NRF) of Korea(2016R1A5A1009405) ; Science Research Center (SRC) program through the National Research Foundation (NRF) of Korea(2016R1A5A1009405) ; Science Research Center (SRC) program through the National Research Foundation (NRF) of Korea(2016R1A5A1009405) ; Science Research Center (SRC) program through the National Research Foundation (NRF) of Korea(2016R1A5A1009405) ; Science Research Center (SRC) program through the National Research Foundation (NRF) of Korea(2016R1A5A1009405) ; Science Research Center (SRC) program through the National Research Foundation (NRF) of Korea(2016R1A5A1009405) ; Science Research Center (SRC) program through the National Research Foundation (NRF) of Korea(2016R1A5A1009405) ; Science Research Center (SRC) program through the National Research Foundation (NRF) of Korea(2016R1A5A1009405) ; Climate Change through the National Research Foundation (NRF) of Korea(2016M1A2940910) ; Climate Change through the National Research Foundation (NRF) of Korea(2016M1A2940910) ; Climate Change through the National Research Foundation (NRF) of Korea(2016M1A2940910) ; Climate Change through the National Research Foundation (NRF) of Korea(2016M1A2940910) ; Climate Change through the National Research Foundation (NRF) of Korea(2016M1A2940910) ; Climate Change through the National Research Foundation (NRF) of Korea(2016M1A2940910) ; Climate Change through the National Research Foundation (NRF) of Korea(2016M1A2940910) ; Climate Change through the National Research Foundation (NRF) of Korea(2016M1A2940910) ; BK21 Plus program through the National Research Foundation (NRF) of Korea(10Z20130011057) ; BK21 Plus program through the National Research Foundation (NRF) of Korea(10Z20130011057) ; BK21 Plus program through the National Research Foundation (NRF) of Korea(10Z20130011057) ; BK21 Plus program through the National Research Foundation (NRF) of Korea(10Z20130011057) ; BK21 Plus program through the National Research Foundation (NRF) of Korea(10Z20130011057) ; BK21 Plus program through the National Research Foundation (NRF) of Korea(10Z20130011057) ; BK21 Plus program through the National Research Foundation (NRF) of Korea(10Z20130011057) ; BK21 Plus program through the National Research Foundation (NRF) of Korea(10Z20130011057) ; Creative Research Initiative (CRI) program through the National Research Foundation (NRF) of Korea(2014R1A2069102) ; Creative Research Initiative (CRI) program through the National Research Foundation (NRF) of Korea(2014R1A2069102) ; Creative Research Initiative (CRI) program through the National Research Foundation (NRF) of Korea(2014R1A2069102) ; Creative Research Initiative (CRI) program through the National Research Foundation (NRF) of Korea(2014R1A2069102) ; Creative Research Initiative (CRI) program through the National Research Foundation (NRF) of Korea(2014R1A2069102) ; Creative Research Initiative (CRI) program through the National Research Foundation (NRF) of Korea(2014R1A2069102) ; Creative Research Initiative (CRI) program through the National Research Foundation (NRF) of Korea(2014R1A2069102) ; Creative Research Initiative (CRI) program through the National Research Foundation (NRF) of Korea(2014R1A2069102) ; Science Research Center (SRC) program through the National Research Foundation (NRF) of Korea(2016R1A5A1009405) ; Science Research Center (SRC) program through the National Research Foundation (NRF) of Korea(2016R1A5A1009405) ; Science Research Center (SRC) program through the National Research Foundation (NRF) of Korea(2016R1A5A1009405) ; Science Research Center (SRC) program through the National Research Foundation (NRF) of Korea(2016R1A5A1009405) ; Science Research Center (SRC) program through the National Research Foundation (NRF) of Korea(2016R1A5A1009405) ; Science Research Center (SRC) program through the National Research Foundation (NRF) of Korea(2016R1A5A1009405) ; Science Research Center (SRC) program through the National Research Foundation (NRF) of Korea(2016R1A5A1009405) ; Science Research Center (SRC) program through the National Research Foundation (NRF) of Korea(2016R1A5A1009405) ; Climate Change through the National Research Foundation (NRF) of Korea(2016M1A2940910) ; Climate Change through the National Research Foundation (NRF) of Korea(2016M1A2940910) ; Climate Change through the National Research Foundation (NRF) of Korea(2016M1A2940910) ; Climate Change through the National Research Foundation (NRF) of Korea(2016M1A2940910) ; Climate Change through the National Research Foundation (NRF) of Korea(2016M1A2940910) ; Climate Change through the National Research Foundation (NRF) of Korea(2016M1A2940910) ; Climate Change through the National Research Foundation (NRF) of Korea(2016M1A2940910) ; Climate Change through the National Research Foundation (NRF) of Korea(2016M1A2940910) ; BK21 Plus program through the National Research Foundation (NRF) of Korea(10Z20130011057) ; BK21 Plus program through the National Research Foundation (NRF) of Korea(10Z20130011057) ; BK21 Plus program through the National Research Foundation (NRF) of Korea(10Z20130011057) ; BK21 Plus program through the National Research Foundation (NRF) of Korea(10Z20130011057) ; BK21 Plus program through the National Research Foundation (NRF) of Korea(10Z20130011057) ; BK21 Plus program through the National Research Foundation (NRF) of Korea(10Z20130011057) ; BK21 Plus program through the National Research Foundation (NRF) of Korea(10Z20130011057) ; BK21 Plus program through the National Research Foundation (NRF) of Korea(10Z20130011057)
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/33585]
专题	合肥物质科学研究院_中科院固体物理研究所
作者单位	1.UNIST, Sch Energy & Chem Engn, Ctr Dimens Controllable Organ Frameworks, 50 UNIST, Ulsan 44919, South Korea 2.UNIST, Sch Nat Sci, 50 UNIST, Ulsan 44919, South Korea 3.Chinese Acad Sci, Anhui Key Lab Nanomat & Nanotechnol, Inst Solid State Phys, Key Lab Mat Phys, Hefei 230031, Anhui, Peoples R China
推荐引用方式 GB/T 7714	Li, Feng,Zhao, Xianglong,Mahmood, Jawed,et al. Macroporous Inverse Opal-like MoXC with Incorporated Mo Vacancies for Significantly Enhanced Hydrogen Evolution[J]. ACS NANO,2017,11(7):7527-7533.
APA	Li, Feng.,Zhao, Xianglong.,Mahmood, Jawed.,Okyay, Mahmut Salt.,Jung, Sun-Min.,...&Baek, Jong-Beom.(2017).Macroporous Inverse Opal-like MoXC with Incorporated Mo Vacancies for Significantly Enhanced Hydrogen Evolution.ACS NANO,11(7),7527-7533.
MLA	Li, Feng,et al."Macroporous Inverse Opal-like MoXC with Incorporated Mo Vacancies for Significantly Enhanced Hydrogen Evolution".ACS NANO 11.7(2017):7527-7533.