Individual and Simultaneous Stripping Voltammetric and Mutual Interference Analysis of Cd2+, Pb2+ and Hg2+ with Reduced Graphene Oxide-Fe3O4 Nanocomposites

doi:10.1016/j.electacta.2015.10.114

CORC > 合肥物质科学研究院 > 中国科学院合肥物质科学研究院 > 技术生物与农业工程研究所

	Individual and Simultaneous Stripping Voltammetric and Mutual Interference Analysis of Cd2+, Pb2+ and Hg2+ with Reduced Graphene Oxide-Fe3O4 Nanocomposites
	Xiong, Shiquan 1; Yang, Bingyi 2; Cai, Dongqing 1; Qiu, Guannan 1; Wu, Zhengyan 1
刊名	ELECTROCHIMICA ACTA
	2015-12-10
卷号	185 期号:无页码:52-61
关键词	Reduced Graphene Oxide-fe3o4 Heavy Metal Ions Electroanalysis Detection
DOI	10.1016/j.electacta.2015.10.114
文献子类	Article
英文摘要	This study attempts to understand the stripping behaviors and mutual impact of different metal ions in electrochemical detection. A reduced graphene oxide-Fe3O4 (rGO-Fe3O4) nanocomposites with small-sized Fe3O4 is prepared by a simple and one-pot synthesis method. The morphology and structure of the nanocomposites are investigated by scanning electron microscopy, energy dispersive X-ray spectroscopy, Fourier transform infrared spectrometer and X-ray diffraction. The electrochemical behaviors of nanocomposite electrode are characterized by cyclic voltammetry and electrochemical impedance spectroscopy. The individual and simultaneous stripping analysis of Cd2+, Pb2+ and Hg2+ using rGO-Fe3O4 electrode are performed by square wave anodic stripping voltammetry (SWASV) under optimized condition, and experimental data show that there are differences in some parameters such as sensitivities and detection limits, etc. To further understand phenomena, a series of interference tests are systematically evaluated by SWASV in detail. The experimental results demonstrate that determination of Cd2+ is easy to be influenced by Pb2+ and Hg2+. At last, the proposed electrode is used to analyze content of Pb2+ in soil sample. The result obtained at the nanocomposite electrode is comparable to that obtained by inductively coupled plasma atomic emission spectroscopy, indicating a good accuracy. The sensor could provide an effective detection and analysis method for heavy metal ions. (C) 2015 Elsevier Ltd. All rights reserved.
WOS关键词	GLASSY-CARBON ELECTRODE ; FUNCTIONALIZED MAGNETITE NANOPARTICLES ; ABSORPTION SPECTROMETRIC DETERMINATION ; HEAVY-METAL IONS ; WASTE-WATER ; ELECTROCHEMICAL DETECTION ; FE3O4 NANOPARTICLES ; REMOVAL ; CHITOSAN ; CADMIUM
WOS研究方向	Electrochemistry
语种	英语
WOS记录号	WOS:000366018700007
资助机构	National Key Foundation for Exploring Scientific Instrument of China(2013YQ17058507) ; National Key Foundation for Exploring Scientific Instrument of China(2013YQ17058507) ; National Key Foundation for Exploring Scientific Instrument of China(2013YQ17058507) ; National Key Foundation for Exploring Scientific Instrument of China(2013YQ17058507) ; Key Program of the Chinese Academy of Sciences(KSZD-EW-Z-022-05) ; Key Program of the Chinese Academy of Sciences(KSZD-EW-Z-022-05) ; Key Program of the Chinese Academy of Sciences(KSZD-EW-Z-022-05) ; Key Program of the Chinese Academy of Sciences(KSZD-EW-Z-022-05) ; National Natural Science Foundation of China(21407151) ; National Natural Science Foundation of China(21407151) ; National Natural Science Foundation of China(21407151) ; National Natural Science Foundation of China(21407151) ; National Key Foundation for Exploring Scientific Instrument of China(2013YQ17058507) ; National Key Foundation for Exploring Scientific Instrument of China(2013YQ17058507) ; National Key Foundation for Exploring Scientific Instrument of China(2013YQ17058507) ; National Key Foundation for Exploring Scientific Instrument of China(2013YQ17058507) ; Key Program of the Chinese Academy of Sciences(KSZD-EW-Z-022-05) ; Key Program of the Chinese Academy of Sciences(KSZD-EW-Z-022-05) ; Key Program of the Chinese Academy of Sciences(KSZD-EW-Z-022-05) ; Key Program of the Chinese Academy of Sciences(KSZD-EW-Z-022-05) ; National Natural Science Foundation of China(21407151) ; National Natural Science Foundation of China(21407151) ; National Natural Science Foundation of China(21407151) ; National Natural Science Foundation of China(21407151)
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/30235]
专题	合肥物质科学研究院_技术生物与农业工程研究所
作者单位	1.Chinese Acad Sci & Anhui Prov, Key Lab Ion Beam Bioengn, Hefei Inst Phys Sci, Hefei 230031, Anhui, Peoples R China 2.Guangdong Pharm Univ, Sch Publ Hlth, Guangzhou 510310, Guangdong, Peoples R China
推荐引用方式 GB/T 7714	Xiong, Shiquan,Yang, Bingyi,Cai, Dongqing,et al. Individual and Simultaneous Stripping Voltammetric and Mutual Interference Analysis of Cd2+, Pb2+ and Hg2+ with Reduced Graphene Oxide-Fe3O4 Nanocomposites[J]. ELECTROCHIMICA ACTA,2015,185(无):52-61.
APA	Xiong, Shiquan,Yang, Bingyi,Cai, Dongqing,Qiu, Guannan,&Wu, Zhengyan.(2015).Individual and Simultaneous Stripping Voltammetric and Mutual Interference Analysis of Cd2+, Pb2+ and Hg2+ with Reduced Graphene Oxide-Fe3O4 Nanocomposites.ELECTROCHIMICA ACTA,185(无),52-61.
MLA	Xiong, Shiquan,et al."Individual and Simultaneous Stripping Voltammetric and Mutual Interference Analysis of Cd2+, Pb2+ and Hg2+ with Reduced Graphene Oxide-Fe3O4 Nanocomposites".ELECTROCHIMICA ACTA 185.无(2015):52-61.