A Fe5C2 nanocatalyst for the preferential synthesis of ethanol via dimethyl oxalate hydrogenation
He, Jia5; Zhao, Yujun5,6; Wang, Yue5; Wang, Junhu2; Zheng, Jian6; Zhang, Hanlei1,4; Zhou, Guangwen1,4; Wang, Chongmin3; Wang, Shengping5; Ma, Xinbin5
刊名CHEMICAL COMMUNICATIONS
2017-05-14
卷号53页码:5376-5379
DOI10.1039/c7cc01644a
英文摘要A Fe-based catalyst exhibits extremely high selectivity (89.6%) besides excellent catalytic activity in gas-phase dimethyl oxalate hydrogenation. The ethanol formation occurs via hydrogenation of methyl acetate instead of ethylene glycol over the active species Fe5C2.
语种英语
WOS记录号WOS:000401118400004
内容类型期刊论文
源URL[http://cas-ir.dicp.ac.cn/handle/321008/152261]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.SUNY Binghamton, Mat Sci & Engn Program, Binghamton, NY 13902 USA
2.Chinese Acad Sci, Dalian Inst Chem Phys, Mossbauer Effect Data Ctr, Dalian, Peoples R China
3.Pacific Northwest Natl Lab, Environm Mol Sci Lab, Richland, WA 99352 USA
4.SUNY Binghamton, Dept Mech, Binghamton, NY 13902 USA
5.Tianjin Univ, Sch Chem Engn & Technol, Collaborat Innovat Ctr Chem Sci & Engn, Key Lab Green Chem Technol,Minist Educ, Tianjin 300072, Peoples R China
6.Pacific Northwest Natl Lab, Inst Integrated Catalysis, Richland, WA 99352 USA
推荐引用方式
GB/T 7714
He, Jia,Zhao, Yujun,Wang, Yue,et al. A Fe5C2 nanocatalyst for the preferential synthesis of ethanol via dimethyl oxalate hydrogenation[J]. CHEMICAL COMMUNICATIONS,2017,53:5376-5379.
APA He, Jia.,Zhao, Yujun.,Wang, Yue.,Wang, Junhu.,Zheng, Jian.,...&Ma, Xinbin.(2017).A Fe5C2 nanocatalyst for the preferential synthesis of ethanol via dimethyl oxalate hydrogenation.CHEMICAL COMMUNICATIONS,53,5376-5379.
MLA He, Jia,et al."A Fe5C2 nanocatalyst for the preferential synthesis of ethanol via dimethyl oxalate hydrogenation".CHEMICAL COMMUNICATIONS 53(2017):5376-5379.
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