Iridium-Catalyzed Reductive Amination of Levulinic Acid to Pyrrolidinones under H-2 in Water

doi:10.1002/cjoc.201600726

	Iridium-Catalyzed Reductive Amination of Levulinic Acid to Pyrrolidinones under H-2 in Water
	Xu, Zhanwei; Yan, Peifang; Jiang, Hong; Liu, Kairui; Zhang, Z. Conrad
刊名	CHINESE JOURNAL OF CHEMISTRY
	2017-05-01
卷号	35 页码:581-585
关键词	Iridium Reductive Amination Hydrogenation Levulinic Acid Biomass
DOI	10.1002/cjoc.201600726
英文摘要	The synthesis of pyrrolidinones from reductive amination of levulinic acid (LA) with primary amines is reported. Pyrrolidinones have various applications such as surfactants, pharmaceutical intermediates, dispersants, and solvents. The half-sandwich Cp* Ir complex (Cp* is 1,2,3,4,5-pentamethylcyclopenta-1,3-diene) coordinated by bipyridine ligand bearing both dimethylamino and ortho-hydroxyl groups showed high catalytic activity for the reductive amination of LA. A range of primary amines, such as aromatic and benzyl amines, were readily converted to corresponding pyrrolidinones in good yields.
语种	英语
WOS记录号	WOS:000404028300009
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/152109]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	Chinese Acad Sci, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Xu, Zhanwei,Yan, Peifang,Jiang, Hong,et al. Iridium-Catalyzed Reductive Amination of Levulinic Acid to Pyrrolidinones under H-2 in Water[J]. CHINESE JOURNAL OF CHEMISTRY,2017,35:581-585.
APA	Xu, Zhanwei,Yan, Peifang,Jiang, Hong,Liu, Kairui,&Zhang, Z. Conrad.(2017).Iridium-Catalyzed Reductive Amination of Levulinic Acid to Pyrrolidinones under H-2 in Water.CHINESE JOURNAL OF CHEMISTRY,35,581-585.
MLA	Xu, Zhanwei,et al."Iridium-Catalyzed Reductive Amination of Levulinic Acid to Pyrrolidinones under H-2 in Water".CHINESE JOURNAL OF CHEMISTRY 35(2017):581-585.