Tandem catalytic synthesis of benzene from CO2 and H-2

doi:10.1039/c7cy00842b

	Tandem catalytic synthesis of benzene from CO2 and H-2
	Zhu, Pengfei 1,3; Sun, Jian 2; Yang, Guohui 3; Liu, Guoguo 3; Zhang, Peipei 3; Yoneyama, Yoshiharu 3; Tsubaki, Noritatsu 3
刊名	CATALYSIS SCIENCE & TECHNOLOGY
	2017-07-07
卷号	7 页码:2695-2699
DOI	10.1039/c7cy00842b
英文摘要	Benzene as an important raw material for production of industrial chemicals is generally synthesized from petroleum and coal tar. Here, we realized the synthesis of benzene from greenhouse CO2 and H-2 with two connected reactors by a tandem catalysis reaction comprising CO2 methanation and CH4 aromatization. The Ni/SiO2 catalyst loaded in the first reactor was used to convert CO2 to CH4, and the formed CH4 was sequentially converted to benzene on the Mo/HZSM-5 catalyst in the second reactor. The benzene formation rate reaches 0.68 mu molg(-1) min(-1) accompanied by a high CO2 conversion of 92%. This concept will provide a new pathway for the direct synthesis of benzene and CO2 utilization.
语种	英语
WOS记录号	WOS:000404887400004
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/152056]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Shaanxi Univ Sci & Technol, Sch Environm Sci & Engn, Xian 710021, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 3.Univ Toyama, Sch Engn, Dept Appl Chem, Gofuku 3190, Toyama 9308555, Japan
推荐引用方式 GB/T 7714	Zhu, Pengfei,Sun, Jian,Yang, Guohui,et al. Tandem catalytic synthesis of benzene from CO2 and H-2[J]. CATALYSIS SCIENCE & TECHNOLOGY,2017,7:2695-2699.
APA	Zhu, Pengfei.,Sun, Jian.,Yang, Guohui.,Liu, Guoguo.,Zhang, Peipei.,...&Tsubaki, Noritatsu.(2017).Tandem catalytic synthesis of benzene from CO2 and H-2.CATALYSIS SCIENCE & TECHNOLOGY,7,2695-2699.
MLA	Zhu, Pengfei,et al."Tandem catalytic synthesis of benzene from CO2 and H-2".CATALYSIS SCIENCE & TECHNOLOGY 7(2017):2695-2699.