Shrimp-shell derived carbon nanodots as precursors to fabricate Fe,N-doped porous graphitic carbon electrocatalysts for efficient oxygen reduction in zinc-air batteries

doi:10.1039/c6qi00059b

CORC > 合肥物质科学研究院 > 中国科学院合肥物质科学研究院 > 中科院固体物理研究所

	Shrimp-shell derived carbon nanodots as precursors to fabricate Fe,N-doped porous graphitic carbon electrocatalysts for efficient oxygen reduction in zinc-air batteries
	Zhang, Xian1,2 ; Liu, Rongrong 1,2; Zang, Yipeng 1,2; Liu, Guoqiang 1,2; Liu, Shengwen 1; Wang, Guozhong 1; Zhang, Yunxia 1; Zhang, Haimin 1; Zhao, Huijun 1,3
刊名	INORGANIC CHEMISTRY FRONTIERS
	2016
卷号	3 期号:7 页码:910-918
DOI	10.1039/c6qi00059b
文献子类	Article
英文摘要	In this work, shrimp-shell derived N-doped carbon nanodots (N-CNs) as carbon and nitrogen sources are assembled into particle-like aggregates by a simple polymerization reaction of pyrrole in the presence of Fe3+ to form Fe containing N-CN/polypyrrole (PPY) composites (Fe-N-CN/PPy). The resulting composites are thermally treated by a facile pyrolysis approach under a N-2 atmosphere to obtain an Fe, N-doped porous graphitic carbon (Fe-N-PGC) material. The results demonstrate that the pyrolytically converted carbon material at 800 degrees C (Fe-N-PGC-800) exhibits an approximately mesoporous structure with a pore size distribution centered at similar to 1.97 nm and similar to 2.8 nm and a surface area of 806.7 m(2) g(-1). As an electrocatalyst for oxygen reduction reaction (ORR) in alkaline media, Fe-N-PGC-800 shows superior ORR catalytic activity with an onset potential of -0.017 V and a limiting current density of 5.42 mA cm(-2) (at -0.4 V, vs. Ag/AgCl), which is superior to that of commercial Pt/C catalysts (onset potential of -0.018 V and a limiting current density of 5.21 mA cm(-2) at -0.4 V, vs. Ag/AgCl). Additionally, Fe-N-PGC-800 also exhibits good ORR activity in acidic media with an onset potential of 0.53 V and a limiting current density of 5.58 mA cm(-2) (at 0.1 V, vs. Ag/AgCl), comparable to that of most reported Fe-based N-doped carbon electrocatalysts. An air cathode made from Fe-N-PGC-800 shows high performance and superior cycling durability in zinc-air batteries (gravimetric energy density of 752 Wh kg(-1)), comparable to that of commercial Pt/C-based batteries (gravimetric energy density of 774 Wh kg(-1)). This work demonstrates the feasibility of utilizing biomass as a starting material to fabricate Fe, N-doped carbon materials as high performance ORR electrocatalysts for practical application in ORR-relevant energy devices.
WOS关键词	NONPRECIOUS-METAL-CATALYSTS ; FUEL-CELLS ; LOW-COST ; BIFUNCTIONAL ELECTROCATALYST ; EVOLUTION REACTIONS ; FE-N/C ; GRAPHENE ; IRON ; NANOCRYSTALS ; NANOTUBES
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:000379491900003
资助机构	CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; Users with Potential Program (Hefei Science Center, CAS) ; Users with Potential Program (Hefei Science Center, CAS) ; Users with Potential Program (Hefei Science Center, CAS) ; Users with Potential Program (Hefei Science Center, CAS) ; Natural Science Foundation of China(51372248 ; Natural Science Foundation of China(51372248 ; Natural Science Foundation of China(51372248 ; Natural Science Foundation of China(51372248 ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; 51432009) ; 51432009) ; 51432009) ; 51432009) ; CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; Users with Potential Program (Hefei Science Center, CAS) ; Users with Potential Program (Hefei Science Center, CAS) ; Users with Potential Program (Hefei Science Center, CAS) ; Users with Potential Program (Hefei Science Center, CAS) ; Natural Science Foundation of China(51372248 ; Natural Science Foundation of China(51372248 ; Natural Science Foundation of China(51372248 ; Natural Science Foundation of China(51372248 ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; 51432009) ; 51432009) ; 51432009) ; 51432009)
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/22487]
专题	合肥物质科学研究院_中科院固体物理研究所
作者单位	1.Chinese Acad Sci, Key Lab Mat Phys, Anhui Key Lab Nanomat & Nanotechnol, Ctr Environm & Energy Nanomat,Inst Solid State Ph, Hefei 230031, Peoples R China 2.Univ Sci & Technol China, Hefei 230026, Peoples R China 3.Griffith Univ, Ctr Clean Environm & Energy, Gold Coast Campus, Southport, Qld 4222, Australia
推荐引用方式 GB/T 7714	Zhang, Xian,Liu, Rongrong,Zang, Yipeng,et al. Shrimp-shell derived carbon nanodots as precursors to fabricate Fe,N-doped porous graphitic carbon electrocatalysts for efficient oxygen reduction in zinc-air batteries[J]. INORGANIC CHEMISTRY FRONTIERS,2016,3(7):910-918.
APA	Zhang, Xian.,Liu, Rongrong.,Zang, Yipeng.,Liu, Guoqiang.,Liu, Shengwen.,...&Zhao, Huijun.(2016).Shrimp-shell derived carbon nanodots as precursors to fabricate Fe,N-doped porous graphitic carbon electrocatalysts for efficient oxygen reduction in zinc-air batteries.INORGANIC CHEMISTRY FRONTIERS,3(7),910-918.
MLA	Zhang, Xian,et al."Shrimp-shell derived carbon nanodots as precursors to fabricate Fe,N-doped porous graphitic carbon electrocatalysts for efficient oxygen reduction in zinc-air batteries".INORGANIC CHEMISTRY FRONTIERS 3.7(2016):910-918.