Metal-organic framework derived nitrogen-doped porous carbon@graphene sandwich-like structured composites as bifunctional electrocatalysts for oxygen reduction and evolution reactions

doi:10.1016/j.carbon.2016.05.021

CORC > 合肥物质科学研究院 > 中国科学院合肥物质科学研究院 > 中科院固体物理研究所

	Metal-organic framework derived nitrogen-doped porous carbon@graphene sandwich-like structured composites as bifunctional electrocatalysts for oxygen reduction and evolution reactions
	Liu, Shengwen 1; Zhang, Haimin 1; Zhao, Qian 1,2; Zhang, Xian1,2 ; Liu, Rongrong 1,2; Ge, Xiao 1,2; Wang, Guozhong 1; Zhao, Huijun 1,3; Cai, Weiping 1
刊名	CARBON
	2016-09-01
卷号	106 期号:无页码:74-83
DOI	10.1016/j.carbon.2016.05.021
文献子类	Article
英文摘要	In this work, we have successfully prepared sandwich-like structured N-doped porous carbon@graphene composites (N-PC@G) derived from sandwich-like structured zeolitic imidazolate framework@graphene oxide (ZIF-8@GO). ZIF-8@GO was obtained by in situ controllable growth of ZIF-8 nanocrystals on both surfaces of graphene oxide (GO) sheets with different contents. Experimental results demonstrate that N-PC@G-0.02 (representing GO amount of 0.02 g in reaction precursors) obtained at 900 degrees C possesses high surface area (1094.3 m(2) g(-1))(,) bimodal-pore structure (micropores and mesopores) and high graphitization degree, exhibiting great potential as a bifunctional electrocatalyst for both ORR and OER. Compared to commercial Pt/C catalyst, the N-PC@G-0.02 shows superior electrocatalytic activity with onset and half-wave potentials of 1.01 V and 0.80 V (vs. RHE), respectively, better durability and high resistance to methanol crossover effect toward ORR in alkaline media. Also, the metal-free N-PC@G-0.02 also exhibits high electrocatalytic activity of OER, comparable to commercial RuO2 catalyst. The superior ORR and OER performance could be due to a synergistic effect between ZIF-8 derived porous carbon and graphene with regard to structure and composition of N-PC@G-0.02 with high surface area, porous structure, and suitable N doping level and type, boosting the catalytic active sites, mass transport and electron transfer. (C) 2016 Elsevier Ltd. All rights reserved.
WOS关键词	CO2 UPTAKE ; EFFICIENT ; HYBRID ; PERFORMANCE ; NANOWIRE ; ARRAYS ; OXIDE ; NANOCOMPOSITES ; MATRIX ; ZIF-8
WOS研究方向	Chemistry ; Materials Science
语种	英语
WOS记录号	WOS:000377544900009
资助机构	CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; Natural Science Foundation of China(51372248 ; Natural Science Foundation of China(51372248 ; Natural Science Foundation of China(51372248 ; Natural Science Foundation of China(51372248 ; Natural Science Foundation of China(51372248 ; Natural Science Foundation of China(51372248 ; Natural Science Foundation of China(51372248 ; Natural Science Foundation of China(51372248 ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; 51432009) ; 51432009) ; 51432009) ; 51432009) ; 51432009) ; 51432009) ; 51432009) ; 51432009) ; CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; CAS Pioneer Hundred Talents Program ; Natural Science Foundation of China(51372248 ; Natural Science Foundation of China(51372248 ; Natural Science Foundation of China(51372248 ; Natural Science Foundation of China(51372248 ; Natural Science Foundation of China(51372248 ; Natural Science Foundation of China(51372248 ; Natural Science Foundation of China(51372248 ; Natural Science Foundation of China(51372248 ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; 51432009) ; 51432009) ; 51432009) ; 51432009) ; 51432009) ; 51432009) ; 51432009) ; 51432009)
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/22134]
专题	合肥物质科学研究院_中科院固体物理研究所
作者单位	1.Chinese Acad Sci, Inst Solid State Phys, Anhui Key Lab Nanomat & Nanotechnol, Key Lab Mat Phys,Ctr Environm & Energy Nanomat, Hefei 230031, Peoples R China 2.Univ Sci & Technol China, Hefei 230026, Peoples R China 3.Griffith Univ, Ctr Clean Environm & Energy, Gold Coast Campus, Qld 4222, Australia
推荐引用方式 GB/T 7714	Liu, Shengwen,Zhang, Haimin,Zhao, Qian,et al. Metal-organic framework derived nitrogen-doped porous carbon@graphene sandwich-like structured composites as bifunctional electrocatalysts for oxygen reduction and evolution reactions[J]. CARBON,2016,106(无):74-83.
APA	Liu, Shengwen.,Zhang, Haimin.,Zhao, Qian.,Zhang, Xian.,Liu, Rongrong.,...&Cai, Weiping.(2016).Metal-organic framework derived nitrogen-doped porous carbon@graphene sandwich-like structured composites as bifunctional electrocatalysts for oxygen reduction and evolution reactions.CARBON,106(无),74-83.
MLA	Liu, Shengwen,et al."Metal-organic framework derived nitrogen-doped porous carbon@graphene sandwich-like structured composites as bifunctional electrocatalysts for oxygen reduction and evolution reactions".CARBON 106.无(2016):74-83.