| Bimetal Doping in Nanoclusters: Synergistic or Counteractive? | |
| Yan, Nan1; Liao, Lingwen1; Yuan, Jinyun2; Lin, Yue-jian3; Weng, Lin-hong3; Yang, Jinlong2; Wu, Zhikun1 | |
| 刊名 | CHEMISTRY OF MATERIALS
 |
| 2016-11-22 | |
| 卷号 | 28期号:22页码:8240-8247 |
| DOI | 10.1021/acs.chemmater.6b03132 |
| 文献子类 | Article |
| 英文摘要 | Doped nanoparticles (especially bimetal doped nanoparticles) have attracted extensive interest not only for fundamental" scientific research but also for application purposes. However, their indefinite composition (structure) and broad distribution hinder an insightful understanding of the interaction between these invasive metals in bimetal doped nanoparticles. Fortunately, atom-precise bimetal doped ultra small nanoparticles (nanoclusters) provide opportunities to obtain such insights. However, atom-precise trimetal nano clusters and their structures have rarely been reported. Here, we successfully dope thiolated Au-25 nanoclusters with Hg and Ag successively by using a biantigalvanic reduction method. We then fully characterize the as-obtained trimetal nanoclusters using multiple techniques (including single-crystal X-ray crystallography), and we demonstrate that the mercury and silver dopings exhibit not only a synergistic but also a counteractive influence on some of the physicochemical properties of Au-25. |
| WOS关键词 | CORE-SHELL NANOPARTICLES ; ANTI-GALVANIC REDUCTION ; PROTECTED GOLD CLUSTERS ; LARGE-SCALE SYNTHESIS ; STRUCTURAL EVOLUTION ; SILVER NANOPARTICLES ; METAL NANOSTRUCTURES ; ELECTRONIC-STRUCTURE ; REPLACEMENT REACTION ; THEORETICAL-ANALYSIS |
| WOS研究方向 | Chemistry ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000388914500017 |
| 资助机构 | Natural Science Foundation of China(21222301 ; Natural Science Foundation of China(21222301 ; Natural Science Foundation of China(21222301 ; Natural Science Foundation of China(21222301 ; Natural Science Foundation of China(21222301 ; Natural Science Foundation of China(21222301 ; Natural Science Foundation of China(21222301 ; Natural Science Foundation of China(21222301 ; National Basic Research Program of China(2013CB934302) ; National Basic Research Program of China(2013CB934302) ; National Basic Research Program of China(2013CB934302) ; National Basic Research Program of China(2013CB934302) ; National Basic Research Program of China(2013CB934302) ; National Basic Research Program of China(2013CB934302) ; National Basic Research Program of China(2013CB934302) ; National Basic Research Program of China(2013CB934302) ; Ministry of Human Resources and Social Security of China ; Ministry of Human Resources and Social Security of China ; Ministry of Human Resources and Social Security of China ; Ministry of Human Resources and Social Security of China ; Ministry of Human Resources and Social Security of China ; Ministry of Human Resources and Social Security of China ; Ministry of Human Resources and Social Security of China ; Ministry of Human Resources and Social Security of China ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; Hefei Science Center, CAS(2015HSCUP003) ; Hefei Science Center, CAS(2015HSCUP003) ; Hefei Science Center, CAS(2015HSCUP003) ; Hefei Science Center, CAS(2015HSCUP003) ; Hefei Science Center, CAS(2015HSCUP003) ; Hefei Science Center, CAS(2015HSCUP003) ; Hefei Science Center, CAS(2015HSCUP003) ; Hefei Science Center, CAS(2015HSCUP003) ; Director Foundation of ISSP(2016DFY05) ; Director Foundation of ISSP(2016DFY05) ; Director Foundation of ISSP(2016DFY05) ; Director Foundation of ISSP(2016DFY05) ; Director Foundation of ISSP(2016DFY05) ; Director Foundation of ISSP(2016DFY05) ; Director Foundation of ISSP(2016DFY05) ; Director Foundation of ISSP(2016DFY05) ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; 21171170 ; 21171170 ; 21171170 ; 21171170 ; 21171170 ; 21171170 ; 21171170 ; 21171170 ; 21501181 ; 21501181 ; 21501181 ; 21501181 ; 21501181 ; 21501181 ; 21501181 ; 21501181 ; 21528303 ; 21528303 ; 21528303 ; 21528303 ; 21528303 ; 21528303 ; 21528303 ; 21528303 ; 21401064) ; 21401064) ; 21401064) ; 21401064) ; 21401064) ; 21401064) ; 21401064) ; 21401064) ; Natural Science Foundation of China(21222301 ; Natural Science Foundation of China(21222301 ; Natural Science Foundation of China(21222301 ; Natural Science Foundation of China(21222301 ; Natural Science Foundation of China(21222301 ; Natural Science Foundation of China(21222301 ; Natural Science Foundation of China(21222301 ; Natural Science Foundation of China(21222301 ; National Basic Research Program of China(2013CB934302) ; National Basic Research Program of China(2013CB934302) ; National Basic Research Program of China(2013CB934302) ; National Basic Research Program of China(2013CB934302) ; National Basic Research Program of China(2013CB934302) ; National Basic Research Program of China(2013CB934302) ; National Basic Research Program of China(2013CB934302) ; National Basic Research Program of China(2013CB934302) ; Ministry of Human Resources and Social Security of China ; Ministry of Human Resources and Social Security of China ; Ministry of Human Resources and Social Security of China ; Ministry of Human Resources and Social Security of China ; Ministry of Human Resources and Social Security of China ; Ministry of Human Resources and Social Security of China ; Ministry of Human Resources and Social Security of China ; Ministry of Human Resources and Social Security of China ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2014FXCX002) ; Hefei Science Center, CAS(2015HSCUP003) ; Hefei Science Center, CAS(2015HSCUP003) ; Hefei Science Center, CAS(2015HSCUP003) ; Hefei Science Center, CAS(2015HSCUP003) ; Hefei Science Center, CAS(2015HSCUP003) ; Hefei Science Center, CAS(2015HSCUP003) ; Hefei Science Center, CAS(2015HSCUP003) ; Hefei Science Center, CAS(2015HSCUP003) ; Director Foundation of ISSP(2016DFY05) ; Director Foundation of ISSP(2016DFY05) ; Director Foundation of ISSP(2016DFY05) ; Director Foundation of ISSP(2016DFY05) ; Director Foundation of ISSP(2016DFY05) ; Director Foundation of ISSP(2016DFY05) ; Director Foundation of ISSP(2016DFY05) ; Director Foundation of ISSP(2016DFY05) ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; 21171170 ; 21171170 ; 21171170 ; 21171170 ; 21171170 ; 21171170 ; 21171170 ; 21171170 ; 21501181 ; 21501181 ; 21501181 ; 21501181 ; 21501181 ; 21501181 ; 21501181 ; 21501181 ; 21528303 ; 21528303 ; 21528303 ; 21528303 ; 21528303 ; 21528303 ; 21528303 ; 21528303 ; 21401064) ; 21401064) ; 21401064) ; 21401064) ; 21401064) ; 21401064) ; 21401064) ; 21401064) |
| 内容类型 | 期刊论文 |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/22017]  |
| 专题 | 合肥物质科学研究院_中科院固体物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Inst Solid State Phys, Key Lab Mat Phys, Anhui Key Lab Nanomat & Nanostruct, Hefei 230031, Peoples R China 2.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China 3.Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Dept Chem, Shanghai 200433, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yan, Nan,Liao, Lingwen,Yuan, Jinyun,et al. Bimetal Doping in Nanoclusters: Synergistic or Counteractive?[J]. CHEMISTRY OF MATERIALS,2016,28(22):8240-8247. |
| APA | Yan, Nan.,Liao, Lingwen.,Yuan, Jinyun.,Lin, Yue-jian.,Weng, Lin-hong.,...&Wu, Zhikun.(2016).Bimetal Doping in Nanoclusters: Synergistic or Counteractive?.CHEMISTRY OF MATERIALS,28(22),8240-8247. |
| MLA | Yan, Nan,et al."Bimetal Doping in Nanoclusters: Synergistic or Counteractive?".CHEMISTRY OF MATERIALS 28.22(2016):8240-8247. |
| 个性服务 |
| 查看访问统计 |
| 相关权益政策 |
| 暂无数据 |
| 收藏/分享 |
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。
修改评论