Sorption of Nickel(II) on a Calcareous Aridisol Soil, China: Batch, XPS, and EXAFS Spectroscopic Investigations | |
Qiang, Shirong1,2,3; Han, Bin1,4; Zhao, Xiaolan1,4; Yang, Yunbo1,4; Shao, Dadong5; Li, Ping1; Liang, Jianjun1; Fan, Qiaohui1 | |
刊名 | SCIENTIFIC REPORTS
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2017-04-25 | |
卷号 | 7 |
DOI | 10.1038/srep46744 |
文献子类 | Article |
英文摘要 | The sorption of Ni(II) on a calcareous aridisol (CA) soil, one of the major soil types in northwestern China, was investigated using batch and extended X-ray absorption fine structure (EXAFS) approaches in a 0.01 mol/L NaClO4 solution at different pH values (6.0-10.0), temperatures (25-60 degrees C) and contact times (2-15 days). Under alkaline conditions, EXAFS analysis showed that the interatomic distances between Ni and O atoms (RNi-O) were approximately 2.04 angstrom with a typical coordination number (CN) of similar to 6.0 O atoms in the contact time range from 2 to 15 days. The RNi-Ni (similar to 3.07 angstrom) suggested that the structure of the Ni(II) adsorbed on the CA soil was basically the same as that of Ni(OH)(2)(s), while the Ni-Al shell (RNi-Al similar to 3.16 angstrom) gradually formed and grew with the increasing contact time. Under weakly acidic conditions, the sorption mechanism of Ni(II) on the CA soil possibly included at least two processes: (i) a fast accumulation dominated by ion exchange and surface complexation and (ii) the formation of a Ni-Al LDH phase over the long term. A high temperature is beneficial to the fixation of Ni(II) on the CA soil and the formation of a Ni-Al LDH. |
WOS关键词 | RAY-ABSORPTION SPECTROSCOPY ; ALUMINUM-OXIDES ; METAL SORPTION ; NI SORPTION ; KINETICS ; AL ; PYROPHYLLITE ; DISSOLUTION ; MECHANISMS ; ADSORPTION |
WOS研究方向 | Science & Technology - Other Topics |
语种 | 英语 |
WOS记录号 | WOS:000400108800001 |
资助机构 | Natural National Science Foundation of China(41573128 ; Natural National Science Foundation of China(41573128 ; Natural National Science Foundation of China(41573128 ; Natural National Science Foundation of China(41573128 ; Natural National Science Foundation of China(41573128 ; Natural National Science Foundation of China(41573128 ; Natural National Science Foundation of China(41573128 ; Natural National Science Foundation of China(41573128 ; Natural National Science Foundation of China(41573128 ; Natural National Science Foundation of China(41573128 ; Natural National Science Foundation of China(41573128 ; Natural National Science Foundation of China(41573128 ; Natural National Science Foundation of China(41573128 ; Natural National Science Foundation of China(41573128 ; Natural National Science Foundation of China(41573128 ; Natural National Science Foundation of China(41573128 ; Key Laboratory Project of Gansu Province(1309RTSA041) ; Key Laboratory Project of Gansu Province(1309RTSA041) ; 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Chinese Academy of Sciences in Lanzhou Center for Oil and Gas Resources, Institute of Geology and Geophysics, CAS ; Chinese Academy of Sciences in Lanzhou Center for Oil and Gas Resources, Institute of Geology and Geophysics, CAS ; Chinese Academy of Sciences in Lanzhou Center for Oil and Gas Resources, Institute of Geology and Geophysics, CAS ; Chinese Academy of Sciences in Lanzhou Center for Oil and Gas Resources, Institute of Geology and Geophysics, CAS ; Chinese Academy of Sciences in Lanzhou Center for Oil and Gas Resources, Institute of Geology and Geophysics, CAS ; Chinese Academy of Sciences in Lanzhou Center for Oil and Gas Resources, Institute of Geology and Geophysics, CAS ; Chinese Academy of Sciences in Lanzhou Center for Oil and Gas Resources, Institute of Geology and Geophysics, CAS ; Chinese Academy of Sciences in Lanzhou Center for Oil and Gas Resources, Institute of Geology and Geophysics, CAS ; Chinese Academy of Sciences in Lanzhou Center for Oil and Gas Resources, Institute of Geology and Geophysics, CAS ; Chinese Academy of Sciences in Lanzhou Center for Oil and Gas Resources, Institute of Geology and Geophysics, CAS ; Chinese Academy of Sciences in Lanzhou Center for Oil and Gas Resources, Institute of Geology and Geophysics, CAS ; Chinese Academy of Sciences in Lanzhou Center for Oil and Gas Resources, Institute of Geology and Geophysics, CAS ; Chinese Academy of Sciences in Lanzhou Center for Oil and Gas Resources, Institute of Geology and Geophysics, CAS ; Chinese Academy of Sciences in Lanzhou Center for Oil and Gas Resources, Institute of Geology and Geophysics, CAS ; 21601179) ; 21601179) ; 21601179) ; 21601179) ; 21601179) ; 21601179) ; 21601179) ; 21601179) ; 21601179) ; 21601179) ; 21601179) ; 21601179) ; 21601179) ; 21601179) ; 21601179) ; 21601179) ; Natural National Science Foundation of China(41573128 ; Natural National Science Foundation of China(41573128 ; Natural National Science Foundation of China(41573128 ; Natural National Science Foundation of China(41573128 ; Natural National Science Foundation of China(41573128 ; Natural National Science Foundation of China(41573128 ; Natural National Science Foundation of China(41573128 ; Natural National Science Foundation of China(41573128 ; Natural National Science Foundation of China(41573128 ; Natural National Science Foundation of China(41573128 ; Natural National Science Foundation of China(41573128 ; Natural National Science Foundation of China(41573128 ; Natural National Science Foundation of China(41573128 ; Natural National Science Foundation of China(41573128 ; Natural National Science Foundation of China(41573128 ; Natural National Science Foundation of China(41573128 ; Key Laboratory Project of Gansu Province(1309RTSA041) ; Key Laboratory Project of Gansu Province(1309RTSA041) ; Key Laboratory Project of Gansu Province(1309RTSA041) ; Key Laboratory Project of Gansu Province(1309RTSA041) ; Key Laboratory Project of Gansu Province(1309RTSA041) ; Key Laboratory Project of Gansu Province(1309RTSA041) ; Key Laboratory Project of Gansu Province(1309RTSA041) ; Key Laboratory Project of Gansu Province(1309RTSA041) ; Key Laboratory Project of Gansu Province(1309RTSA041) ; Key Laboratory Project of Gansu Province(1309RTSA041) ; Key Laboratory Project of Gansu Province(1309RTSA041) ; Key Laboratory Project of Gansu Province(1309RTSA041) ; Key Laboratory Project of Gansu Province(1309RTSA041) ; Key Laboratory Project of Gansu Province(1309RTSA041) ; Key Laboratory Project of Gansu Province(1309RTSA041) ; Key Laboratory Project of Gansu Province(1309RTSA041) ; Chinese Academy of Sciences in Lanzhou Center for Oil and Gas Resources, Institute of Geology and Geophysics, CAS ; Chinese Academy of Sciences in Lanzhou Center for Oil and Gas Resources, Institute of Geology and Geophysics, CAS ; Chinese Academy of Sciences in Lanzhou Center for Oil and Gas Resources, Institute of Geology and Geophysics, CAS ; Chinese Academy of Sciences in Lanzhou Center for Oil and Gas Resources, Institute of Geology and Geophysics, CAS ; Chinese Academy of Sciences in Lanzhou Center for Oil and Gas Resources, Institute of Geology and Geophysics, CAS ; Chinese Academy of Sciences in Lanzhou Center for Oil and Gas Resources, Institute of Geology and Geophysics, CAS ; Chinese Academy of Sciences in Lanzhou Center for Oil and Gas Resources, Institute of Geology and Geophysics, CAS ; Chinese Academy of Sciences in Lanzhou Center for Oil and Gas Resources, Institute of Geology and Geophysics, CAS ; Chinese Academy of Sciences in Lanzhou Center for Oil and Gas Resources, Institute of Geology and Geophysics, CAS ; Chinese Academy of Sciences in Lanzhou Center for Oil and Gas Resources, Institute of Geology and Geophysics, CAS ; Chinese Academy of Sciences in Lanzhou Center for Oil and Gas Resources, Institute of Geology and Geophysics, CAS ; Chinese Academy of Sciences in Lanzhou Center for Oil and Gas Resources, Institute of Geology and Geophysics, CAS ; Chinese Academy of Sciences in Lanzhou Center for Oil and Gas Resources, Institute of Geology and Geophysics, CAS ; Chinese Academy of Sciences in Lanzhou Center for Oil and Gas Resources, Institute of Geology and Geophysics, CAS ; 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内容类型 | 期刊论文 |
源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/33489] ![]() |
专题 | 合肥物质科学研究院_中科院等离子体物理研究所 |
作者单位 | 1.Chinese Acad Sci, Key Lab Petr Resources, Gansu Prov CAS Key Lab Petr Resources Res, Inst Geol & Geophys, Lanzhou 730000, Gansu, Peoples R China 2.Lanzhou Univ, Key Lab Preclin Study New Drugs Gansu Prov, Sch Basic Med Sci, 199 Donggang West Rd, Lanzhou 73000, Peoples R China 3.Lanzhou Univ, Inst Physiol, Sch Basic Med Sci, 199 Donggang West Rd, Lanzhou 73000, Peoples R China 4.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 5.Chinese Acad Sci, Inst Plasma Phys, Hefei 230031, Peoples R China |
推荐引用方式 GB/T 7714 | Qiang, Shirong,Han, Bin,Zhao, Xiaolan,et al. Sorption of Nickel(II) on a Calcareous Aridisol Soil, China: Batch, XPS, and EXAFS Spectroscopic Investigations[J]. SCIENTIFIC REPORTS,2017,7. |
APA | Qiang, Shirong.,Han, Bin.,Zhao, Xiaolan.,Yang, Yunbo.,Shao, Dadong.,...&Fan, Qiaohui.(2017).Sorption of Nickel(II) on a Calcareous Aridisol Soil, China: Batch, XPS, and EXAFS Spectroscopic Investigations.SCIENTIFIC REPORTS,7. |
MLA | Qiang, Shirong,et al."Sorption of Nickel(II) on a Calcareous Aridisol Soil, China: Batch, XPS, and EXAFS Spectroscopic Investigations".SCIENTIFIC REPORTS 7(2017). |
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