Synthesis of Diesel and Jet Fuel Range Alkanes with Furfural and Angelica Lactone | |
Wang, Aiqin1,2; Li, Guangyi2; Yang, Xiaofeng2; Cong, Yu2; Wang, Xiaodong2; Li, Ning1,2; Xu, Jilei2; Zhang, Tao1,2 | |
刊名 | ACS CATALYSIS
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2017-09-01 | |
卷号 | 7期号:9页码:5880-5886 |
关键词 | lignocellulose diesel and jet fuels angelica lactone aldol condensation hydrodeoxygenation |
英文摘要 | A route was developed for the synthesis of diesel and jet fuel range C-9 and C-10 alkanes with furfural and angelica lactone, which can be obtained from hemicellulose and cellulose. It was found that angelica lactone is more reactive than levulinic acid or its other derivates in the aldol condensation with furfural. Among the investigated catalysts, Mn2O3 was found to be the most active and was very stable for the aldol condensation of furfural and angelica lactone. Over Mn2O3, a high carbon yield of C-10 oxygenates (about 96%) can be achieved by the aldol condensation of furfural and angelica lactone under mild conditions (353 K, 4 h). By the hydrogenation and hydrodeoxygenation of the aldol condensation product over the Pd/C and Pd-FeOx/SiO2 catalysts, high carbon yields (similar to 96%) of C-9 and C-10 alkanes were obtained. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Chemistry, Physical |
研究领域[WOS] | Chemistry |
关键词[WOS] | WOODY BIOMASS SOLIDS ; HIGH-QUALITY DIESEL ; GAMMA-VALEROLACTONE ; CATALYTIC CONVERSION ; LIGNOCELLULOSIC BIOMASS ; TRANSPORTATION FUELS ; BIMETALLIC CATALYSTS ; ALDOL-CONDENSATION ; LIQUID ALKANES ; LEVULINIC ACID |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000410005700036 |
内容类型 | 期刊论文 |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/150040] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, iChEM Collaborat Innovat Ctr Chem Energy Mat, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Aiqin,Li, Guangyi,Yang, Xiaofeng,et al. Synthesis of Diesel and Jet Fuel Range Alkanes with Furfural and Angelica Lactone[J]. ACS CATALYSIS,2017,7(9):5880-5886. |
APA | Wang, Aiqin.,Li, Guangyi.,Yang, Xiaofeng.,Cong, Yu.,Wang, Xiaodong.,...&Zhang, Tao.(2017).Synthesis of Diesel and Jet Fuel Range Alkanes with Furfural and Angelica Lactone.ACS CATALYSIS,7(9),5880-5886. |
MLA | Wang, Aiqin,et al."Synthesis of Diesel and Jet Fuel Range Alkanes with Furfural and Angelica Lactone".ACS CATALYSIS 7.9(2017):5880-5886. |
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