Catalytic Oxidation of Alcohol to Carboxylic Acid with a Hydrophobic Cobalt Catalyst in Hydrocarbon Solvent | |
Chen, Chen1; Zhao, Li1,2; Liu, Meng1,2; Shi, Song1; Xu, Jie1; Gao, Jin1; Wang, Min1 | |
刊名 | CHEMISTRY-AN ASIAN JOURNAL
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2017-09-19 | |
卷号 | 12期号:18页码:2404-2409 |
关键词 | alcohol cobalt hydrocarbon solvent hydrophobic oxidation |
英文摘要 | A hydrophobic cobalt catalyst was synthesized and proved to be effective in alcohol oxidation under the assistance of hydrocarbon solvent with oxygen as the terminal oxidant. A series of catalysts with different water contact angles was applied to investigate the hydrophobic effect. Further insight into the reaction process was gained by reaction kinetics, isotopic effect, etc. It showed that the hydrocarbon solvent participated in the alcohol oxidation, and with the aid of the in situ generated free radicals, the -C-H bond was smoothly activated and the alcohol was converted to carbonyl compounds. The hydrophobic effect promoted the alcohol oxidation by affecting the solvent oxidation. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Chemistry, Multidisciplinary |
研究领域[WOS] | Chemistry |
关键词[WOS] | SELECTIVE AEROBIC OXIDATION ; BASE-FREE CONDITIONS ; OXIDE NANOPARTICLES ; ALIPHATIC-ALCOHOLS ; BENZYLIC ALCOHOLS ; DEHYDROGENATION ; WETTABILITY ; CHEMISTRY ; EFFICIENT ; COMPLEXES |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000411081300016 |
内容类型 | 期刊论文 |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/150027] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Natl Lab Clean Energy, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, Chen,Zhao, Li,Liu, Meng,et al. Catalytic Oxidation of Alcohol to Carboxylic Acid with a Hydrophobic Cobalt Catalyst in Hydrocarbon Solvent[J]. CHEMISTRY-AN ASIAN JOURNAL,2017,12(18):2404-2409. |
APA | Chen, Chen.,Zhao, Li.,Liu, Meng.,Shi, Song.,Xu, Jie.,...&Wang, Min.(2017).Catalytic Oxidation of Alcohol to Carboxylic Acid with a Hydrophobic Cobalt Catalyst in Hydrocarbon Solvent.CHEMISTRY-AN ASIAN JOURNAL,12(18),2404-2409. |
MLA | Chen, Chen,et al."Catalytic Oxidation of Alcohol to Carboxylic Acid with a Hydrophobic Cobalt Catalyst in Hydrocarbon Solvent".CHEMISTRY-AN ASIAN JOURNAL 12.18(2017):2404-2409. |
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