One-pot synthesis of 2-hydroxymethyl-5-methylpyrazine from renewable 1,3-dihydroxyacetone | |
Zhao, Jian2; Song, Lei1,2; Zheng, Mingyuan1; Pang, Jifeng1; Sebastian, Joby1; Wang, Wentao1; Qu, Minjie2; Wang, Xinhong2; Zhang, Tao1 | |
刊名 | GREEN CHEMISTRY
![]() |
2017-08-07 | |
卷号 | 19期号:15页码:3515-3519 |
英文摘要 | An efficient and green method for the synthesis of 2-hydroxymethyl-5-methylpyrazine was achieved from biomass derived 1,3-dihydroxyacetone and diammonium phosphate via a one-pot reaction. The product yield was as high as 72% under optimized conditions of pH = 8.0-9.1 at 90 degrees C for 1 hour in a dioxane and water mixture as a solvent. A possible reaction mechanism was proposed according to the reaction kinetics, NMR and in situ ATR-IR characterization studies. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Chemistry, Multidisciplinary |
研究领域[WOS] | Chemistry |
关键词[WOS] | REDUCTIVE AMINATION ; PRIMARY AMINES ; ETHYLENE-GLYCOL ; CATALYSTS ; ACID ; 2-METHYLPYRAZINE ; CONVERSION ; OXIDATION ; PYRAZINE ; AMMONIA |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000406615800005 |
内容类型 | 期刊论文 |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/149851] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Dalian Polytech Univ, Mat Sci & Engn, Dalian 116034, Peoples R China |
推荐引用方式 GB/T 7714 | Zhao, Jian,Song, Lei,Zheng, Mingyuan,et al. One-pot synthesis of 2-hydroxymethyl-5-methylpyrazine from renewable 1,3-dihydroxyacetone[J]. GREEN CHEMISTRY,2017,19(15):3515-3519. |
APA | Zhao, Jian.,Song, Lei.,Zheng, Mingyuan.,Pang, Jifeng.,Sebastian, Joby.,...&Zhang, Tao.(2017).One-pot synthesis of 2-hydroxymethyl-5-methylpyrazine from renewable 1,3-dihydroxyacetone.GREEN CHEMISTRY,19(15),3515-3519. |
MLA | Zhao, Jian,et al."One-pot synthesis of 2-hydroxymethyl-5-methylpyrazine from renewable 1,3-dihydroxyacetone".GREEN CHEMISTRY 19.15(2017):3515-3519. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论