One-pot synthesis of 2-hydroxymethyl-5-methylpyrazine from renewable 1,3-dihydroxyacetone

	One-pot synthesis of 2-hydroxymethyl-5-methylpyrazine from renewable 1,3-dihydroxyacetone
	Zhao, Jian 2; Song, Lei 1,2; Zheng, Mingyuan 1; Pang, Jifeng 1; Sebastian, Joby 1; Wang, Wentao 1; Qu, Minjie 2; Wang, Xinhong 2; Zhang, Tao 1
刊名	GREEN CHEMISTRY
	2017-08-07
卷号	19 期号:15 页码:3515-3519
英文摘要	An efficient and green method for the synthesis of 2-hydroxymethyl-5-methylpyrazine was achieved from biomass derived 1,3-dihydroxyacetone and diammonium phosphate via a one-pot reaction. The product yield was as high as 72% under optimized conditions of pH = 8.0-9.1 at 90 degrees C for 1 hour in a dioxane and water mixture as a solvent. A possible reaction mechanism was proposed according to the reaction kinetics, NMR and in situ ATR-IR characterization studies.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Multidisciplinary
研究领域[WOS]	Chemistry
关键词[WOS]	REDUCTIVE AMINATION ; PRIMARY AMINES ; ETHYLENE-GLYCOL ; CATALYSTS ; ACID ; 2-METHYLPYRAZINE ; CONVERSION ; OXIDATION ; PYRAZINE ; AMMONIA
收录类别	SCI
语种	英语
WOS记录号	WOS:000406615800005
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/149851]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Dalian Polytech Univ, Mat Sci & Engn, Dalian 116034, Peoples R China
推荐引用方式 GB/T 7714	Zhao, Jian,Song, Lei,Zheng, Mingyuan,et al. One-pot synthesis of 2-hydroxymethyl-5-methylpyrazine from renewable 1,3-dihydroxyacetone[J]. GREEN CHEMISTRY,2017,19(15):3515-3519.
APA	Zhao, Jian.,Song, Lei.,Zheng, Mingyuan.,Pang, Jifeng.,Sebastian, Joby.,...&Zhang, Tao.(2017).One-pot synthesis of 2-hydroxymethyl-5-methylpyrazine from renewable 1,3-dihydroxyacetone.GREEN CHEMISTRY,19(15),3515-3519.
MLA	Zhao, Jian,et al."One-pot synthesis of 2-hydroxymethyl-5-methylpyrazine from renewable 1,3-dihydroxyacetone".GREEN CHEMISTRY 19.15(2017):3515-3519.