Metal-Free Oxidation of Glycerol over Nitrogen-Containing Carbon Nanotubes

	Metal-Free Oxidation of Glycerol over Nitrogen-Containing Carbon Nanotubes
	Gupta, Neeraj 2; Khavryuchenko, Oleksiy 3; Villa, Alberto 4; Su, Dangsheng 1,2
刊名	CHEMSUSCHEM
	2017-08-10
卷号	10 期号:15 页码:3030-3034
关键词	biomass conversion carbon nanotubes glycerol metal-free oxidation NCNTs
英文摘要	Nitrogen rich carbon nanotubes have been used as a metal free catalyst for the conversion of glycerol into dihydroxyacetone using tert-butyl hydroperoxide as an oxidant. Pyridine nitrogen groups embedded in a carbon matrix are identified as active sites for the reaction. Computational studies have demonstrated that oxidation of pyridine groups to pyridine oxime followed by hydrogen abstraction from secondary alcohol is likely responsible for the oxidation process.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Multidisciplinary
研究领域[WOS]	Chemistry
关键词[WOS]	SELECTIVE OXIDATION ; AEROBIC OXIDATION ; LIQUID-PHASE ; CATALYST ; NANOPARTICLES ; ALCOHOLS ; DIHYDROXYACETONE ; ACTIVATION ; CHEMICALS
收录类别	SCI
语种	英语
WOS记录号	WOS:000407385500004
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/149827]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China 2.Chinese Acad Sci, Catalysis Div, IMR Shenyang Natl Lab, Shenyang 110016, Liaoning, Peoples R China 3.TMM LLC, Res & Dev Dept, Volodymyrska Str 49a, Kiev, Ukraine 4.Univ Milan, Dipartimento Chim, Via Golgi 19, I-20133 Milan, Italy
推荐引用方式 GB/T 7714	Gupta, Neeraj,Khavryuchenko, Oleksiy,Villa, Alberto,et al. Metal-Free Oxidation of Glycerol over Nitrogen-Containing Carbon Nanotubes[J]. CHEMSUSCHEM,2017,10(15):3030-3034.
APA	Gupta, Neeraj,Khavryuchenko, Oleksiy,Villa, Alberto,&Su, Dangsheng.(2017).Metal-Free Oxidation of Glycerol over Nitrogen-Containing Carbon Nanotubes.CHEMSUSCHEM,10(15),3030-3034.
MLA	Gupta, Neeraj,et al."Metal-Free Oxidation of Glycerol over Nitrogen-Containing Carbon Nanotubes".CHEMSUSCHEM 10.15(2017):3030-3034.