Rhodium(III)-catalyzed synthesis of indanones via C-H activation of phenacyl phosphoniums and coupling with olefins

	Rhodium(III)-catalyzed synthesis of indanones via C-H activation of phenacyl phosphoniums and coupling with olefins
	Yang, Xifa 1,2; Li, Xingwei 1; Li, Yunyun 1,2; Kong, Lingheng 1,2
刊名	ORGANIC CHEMISTRY FRONTIERS
	2017-11-01
卷号	4 期号:11 页码:2114-2118
英文摘要	Phosphonium ylide acts as an efficient bifunctional directing group in Rh(III)-catalyzed C-H activation of arenes and oxidative coupling with activated olefins, leading to facile construction of indanones via a sequence of oxidative olefination and carboannulation. The phosphonium moiety functions as an oxophilic group, and dephosphination triggers a nucleophilic cyclization.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Organic
研究领域[WOS]	Chemistry
关键词[WOS]	CHIRAL 3-SUBSTITUTED INDANONES ; SPONGE TERPIOS-HOSHINOTA ; BOND FUNCTIONALIZATION ; N-HETEROCYCLES ; ENANTIOSELECTIVE SYNTHESIS ; CATALYZED ANNULATION ; DIAZO-COMPOUNDS ; ALKYNES ; ALKENES ; DERIVATIVES
收录类别	SCI
语种	英语
WOS记录号	WOS:000413826400005
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/149756]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Yang, Xifa,Li, Xingwei,Li, Yunyun,et al. Rhodium(III)-catalyzed synthesis of indanones via C-H activation of phenacyl phosphoniums and coupling with olefins[J]. ORGANIC CHEMISTRY FRONTIERS,2017,4(11):2114-2118.
APA	Yang, Xifa,Li, Xingwei,Li, Yunyun,&Kong, Lingheng.(2017).Rhodium(III)-catalyzed synthesis of indanones via C-H activation of phenacyl phosphoniums and coupling with olefins.ORGANIC CHEMISTRY FRONTIERS,4(11),2114-2118.
MLA	Yang, Xifa,et al."Rhodium(III)-catalyzed synthesis of indanones via C-H activation of phenacyl phosphoniums and coupling with olefins".ORGANIC CHEMISTRY FRONTIERS 4.11(2017):2114-2118.