SYNTHESIS AND CRYSTAL-STRUCTURE OF THE TRIS(CYCLOPENTADIENYL)PHENYL COMPLEX OF NEODYMIUM, (LI-BULLET-3DME)[(ETA-5-C5H5)3NDC6H5]

	SYNTHESIS AND CRYSTAL-STRUCTURE OF THE TRIS(CYCLOPENTADIENYL)PHENYL COMPLEX OF NEODYMIUM, (LI-BULLET-3DME)[(ETA-5-C5H5)3NDC6H5]
	GAO HR ; SHEN Q ; HU JY ; JIN SC ; LIN YH
刊名	journal of organometallic chemistry
	1992
卷号	427 期号:2 页码:141-149
关键词	HIGHLY REACTIVE ORGANOLANTHANIDES CHEMISTRY
ISSN号	0022-328x
中文摘要	(li.3dme)[eta(5)-c5h5)3ndc6h5], 1 was synthesized by the reaction of ndcl3.2licl, 2 equivalents of cyclopentadienylsodium and one equivalent of phenyllithium in thf at -78-degrees-c, and crystallized from thf and dme. the crystal structure of 1 was determined by x-ray diffraction method at -80-degrees-c. the crystal of 1 is triclinic, space group p1bar with a = 15.752(6), b = 16.232(3), c = 23.038(7) angstrom, alpha = 108.81(2), beta = 93.31(3), gamma = 108.38(2)-degrees, z = 6 and d = 1.33 g/cm3. least-squares refinement (5732 observed reflections) led to a final r of 0.053. the complex consists of disconnected ion pairs of (li.3dme)+ and [(eta(5)-c5h5)3ndc6h5]-. the neodymium atom was connected to three eta(5)-bonded cyclopentadienyls and one sigma-bonded phenyl in a distorted tetrahedral arrangement with nd-c(sigma-) 2.593(17), 2.613(13) and 2.601(13) angstrom.
收录类别	SCI收录期刊论文
语种	英语
公开日期	2011-01-19 ; 2011-06-10
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/37291]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	GAO HR,SHEN Q,HU JY,et al. SYNTHESIS AND CRYSTAL-STRUCTURE OF THE TRIS(CYCLOPENTADIENYL)PHENYL COMPLEX OF NEODYMIUM, (LI-BULLET-3DME)[(ETA-5-C5H5)3NDC6H5][J]. journal of organometallic chemistry,1992,427(2):141-149.
APA	GAO HR,SHEN Q,HU JY,JIN SC,&LIN YH.(1992).SYNTHESIS AND CRYSTAL-STRUCTURE OF THE TRIS(CYCLOPENTADIENYL)PHENYL COMPLEX OF NEODYMIUM, (LI-BULLET-3DME)[(ETA-5-C5H5)3NDC6H5].journal of organometallic chemistry,427(2),141-149.
MLA	GAO HR,et al."SYNTHESIS AND CRYSTAL-STRUCTURE OF THE TRIS(CYCLOPENTADIENYL)PHENYL COMPLEX OF NEODYMIUM, (LI-BULLET-3DME)[(ETA-5-C5H5)3NDC6H5]".journal of organometallic chemistry 427.2(1992):141-149.