ELECTROCHEMICAL-BEHAVIOR OF N-METHYL-N'-HEXADECYLVIOLOGEN MONOLAYERS ON SILVER ELECTRODES - EFFECTS OF COUNTERIONS

	ELECTROCHEMICAL-BEHAVIOR OF N-METHYL-N'-HEXADECYLVIOLOGEN MONOLAYERS ON SILVER ELECTRODES - EFFECTS OF COUNTERIONS
	YE SY ; KIM JH ; UPHAUS RA ; COTTON TM ; LU TG ; DONG SJ
刊名	thin solid films
	1992
卷号	210 期号:1-2 页码:822-824
关键词	LANGMUIR-BLODGETT METHOD SURFACES GOLD
ISSN号	0040-6090
通讯作者	ye sy
中文摘要	n-methyl-n'-hexadecylviologen (c16mv) has been the subject of several electrochemical and spectroelectrochemical studies which characterized the species present in various redox states for c16mv monolayers on silver electrode surfaces. both self-assembled monolayers (sa) and langmuir-blodgett (lb) transferred systems have been studied. these indicated inconsistencies regarding the presence or absence of splitting of the first reduction peak in its cyclic voltammogram (cv). the present study demonstrates the important influence of the specific anionic species present in the supporting electrolyte. splitting may or may not take place, depending on the size and relative strength of the adsorption of specific anions contributed by the supporting electrolyte. small, strongly adsorbing anions such as iodide produced peak splitting in the cv of c16mv monolayers; bulky but weakly adsorbing anions such as perchlorate may disrupt the ordered structure of monolayers but produce no splitting. ancillary data provided by surface enhanced raman spectroscopy (sers) was consistent with the electrochemical measurements.
收录类别	SCI收录期刊论文
语种	英语
公开日期	2011-01-19 ; 2011-06-10
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/37281]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	YE SY,KIM JH,UPHAUS RA,et al. ELECTROCHEMICAL-BEHAVIOR OF N-METHYL-N'-HEXADECYLVIOLOGEN MONOLAYERS ON SILVER ELECTRODES - EFFECTS OF COUNTERIONS[J]. thin solid films,1992,210(1-2):822-824.
APA	YE SY,KIM JH,UPHAUS RA,COTTON TM,LU TG,&DONG SJ.(1992).ELECTROCHEMICAL-BEHAVIOR OF N-METHYL-N'-HEXADECYLVIOLOGEN MONOLAYERS ON SILVER ELECTRODES - EFFECTS OF COUNTERIONS.thin solid films,210(1-2),822-824.
MLA	YE SY,et al."ELECTROCHEMICAL-BEHAVIOR OF N-METHYL-N'-HEXADECYLVIOLOGEN MONOLAYERS ON SILVER ELECTRODES - EFFECTS OF COUNTERIONS".thin solid films 210.1-2(1992):822-824.