X-RAY PHOTOELECTRON-SPECTRA OF SOME BIOINORGANIC COMPLEXES OF THE RARE-EARTHS WITH N-ACETYLALANINE

	X-RAY PHOTOELECTRON-SPECTRA OF SOME BIOINORGANIC COMPLEXES OF THE RARE-EARTHS WITH N-ACETYLALANINE
	NIU CJ ; JIA YQ
刊名	spectrochimica acta part a-molecular and biomolecular spectroscopy
	1993
卷号	49 期号:7 页码:947-951
关键词	PHOTOEMISSION SPECTRA SPECTROSCOPY CERIUM
ISSN号	0584-8539
中文摘要	x-ray photoelectron spectra of some bioinorganic complexes of la, ce, pt, nd, sm and eu with n-acetylalanine have been measured and the 3d5/2 and 3d3/2 main peaks and their satellites have also been assigned. ne spin-orbit splitting between the 3d5/2 and 3d3/2 core-level of the rare earth ion in these complexes becomes slightly larger than that of the free rare earth atom due to the effect of the crystal field. the satellite for the 3d main peaks of la in the solid state complex are in higher binding energy region and may be attributable to the l --> 4f charge-transfer shake-up process. the satellites for the 3d main peaks of ce, pr, nd, sm and eu are in the lower binding energy region and may be attributable to the 4f --> l charge-transfer shake-down process.
收录类别	SCI收录期刊论文
语种	英语
公开日期	2011-01-19 ; 2011-06-10
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/36181]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	NIU CJ,JIA YQ. X-RAY PHOTOELECTRON-SPECTRA OF SOME BIOINORGANIC COMPLEXES OF THE RARE-EARTHS WITH N-ACETYLALANINE[J]. spectrochimica acta part a-molecular and biomolecular spectroscopy,1993,49(7):947-951.
APA	NIU CJ,&JIA YQ.(1993).X-RAY PHOTOELECTRON-SPECTRA OF SOME BIOINORGANIC COMPLEXES OF THE RARE-EARTHS WITH N-ACETYLALANINE.spectrochimica acta part a-molecular and biomolecular spectroscopy,49(7),947-951.
MLA	NIU CJ,et al."X-RAY PHOTOELECTRON-SPECTRA OF SOME BIOINORGANIC COMPLEXES OF THE RARE-EARTHS WITH N-ACETYLALANINE".spectrochimica acta part a-molecular and biomolecular spectroscopy 49.7(1993):947-951.