SYNTHESIS, SOLUTION DYNAMICS AND X-RAY CRYSTAL-STRUCTURES OF NEODYMIUM-YLIDE COMPLEXES, [(C(5)H(4)R)(3)NDCH2P(ME)PH(2)] (R=H, BU(T))

	SYNTHESIS, SOLUTION DYNAMICS AND X-RAY CRYSTAL-STRUCTURES OF NEODYMIUM-YLIDE COMPLEXES, [(C(5)H(4)R)(3)NDCH2P(ME)PH(2)] (R=H, BU(T))
	WONG WK ; GUAN JW ; SHEN Q ; ZHANG LL ; LIN YG ; WONG WT
刊名	polyhedron
	1995
卷号	14 期号:2 页码:277-283
关键词	HIGHLY REACTIVE ORGANOLANTHANIDES ORGANOMETALLIC COMPOUNDS CHEMISTRY LIGANDS
ISSN号	0277-5387
通讯作者	wong wk
中文摘要	the interaction of [(c(5)h(4)r)(2)ndcl.2licl] (r = h, bu(t)) with one equivalent of li[(ch2)(ch2)pph(2)] in refluxing tetrahydrofuran gave the purplish-blue complex [(c(5)h(4)r)(3)ndch2p(me)ph(2)] in 50% yield. the compounds have been fully characterized by analytical, spectroscopic and x-ray diffraction methods. variable temperature p-31{h-1} nmr spectroscopy indicated the existence of the following equilibrium: [(c(5)h(4)r)(3)ndch2p(me)ph(2)] + thf reversible arrow (c(5)h(4)r)(3)nd(thf) + ch2=p(me)ph(2). at room temperature, the exchange between the coordinated and free ylide ligand is slow on the nmr time scale.
收录类别	SCI收录期刊论文
语种	英语
公开日期	2010-12-30 ; 2011-06-10
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/26725]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	WONG WK,GUAN JW,SHEN Q,et al. SYNTHESIS, SOLUTION DYNAMICS AND X-RAY CRYSTAL-STRUCTURES OF NEODYMIUM-YLIDE COMPLEXES, [(C(5)H(4)R)(3)NDCH2P(ME)PH(2)] (R=H, BU(T))[J]. polyhedron,1995,14(2):277-283.
APA	WONG WK,GUAN JW,SHEN Q,ZHANG LL,LIN YG,&WONG WT.(1995).SYNTHESIS, SOLUTION DYNAMICS AND X-RAY CRYSTAL-STRUCTURES OF NEODYMIUM-YLIDE COMPLEXES, [(C(5)H(4)R)(3)NDCH2P(ME)PH(2)] (R=H, BU(T)).polyhedron,14(2),277-283.
MLA	WONG WK,et al."SYNTHESIS, SOLUTION DYNAMICS AND X-RAY CRYSTAL-STRUCTURES OF NEODYMIUM-YLIDE COMPLEXES, [(C(5)H(4)R)(3)NDCH2P(ME)PH(2)] (R=H, BU(T))".polyhedron 14.2(1995):277-283.