INTRAANNULAR AND INTERANNULAR SUBSTITUENT MIGRATION AND INTRAMOLECULAR IPSO SUBSTITUTION OF BIPHENYL DERIVATIVES IN MASS-SPECTROMETRY | |
TU YP ; LIU YQ ; LIU SY | |
刊名 | rapid communications in mass spectrometry |
1995 | |
卷号 | 9期号:4页码:300-304 |
关键词 | ELECTRON-IMPACT SPECTRA ION CATIONS TOLUENE |
ISSN号 | 0951-4198 |
通讯作者 | tu yp |
中文摘要 | biphenyl derivatives undergo extensive intraannular substituent migrations and subsequent intramolecular ipso substitutions giving rise to a fluorenyl cation and a biphenylene radical cation as common products in mass spectrometry. for biphenyls bearing an alkyl group, interannular substituent migration resulting in a substituted tropylium ion is also observed. electron-withdrawing groups are found to be much more favourable to these reactions than the electron-donating ones. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
公开日期 | 2010-12-30 ; 2011-06-10 |
内容类型 | 期刊论文 |
源URL | [http://ir.ciac.jl.cn/handle/322003/26667] |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | TU YP,LIU YQ,LIU SY. INTRAANNULAR AND INTERANNULAR SUBSTITUENT MIGRATION AND INTRAMOLECULAR IPSO SUBSTITUTION OF BIPHENYL DERIVATIVES IN MASS-SPECTROMETRY[J]. rapid communications in mass spectrometry,1995,9(4):300-304. |
APA | TU YP,LIU YQ,&LIU SY.(1995).INTRAANNULAR AND INTERANNULAR SUBSTITUENT MIGRATION AND INTRAMOLECULAR IPSO SUBSTITUTION OF BIPHENYL DERIVATIVES IN MASS-SPECTROMETRY.rapid communications in mass spectrometry,9(4),300-304. |
MLA | TU YP,et al."INTRAANNULAR AND INTERANNULAR SUBSTITUENT MIGRATION AND INTRAMOLECULAR IPSO SUBSTITUTION OF BIPHENYL DERIVATIVES IN MASS-SPECTROMETRY".rapid communications in mass spectrometry 9.4(1995):300-304. |
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