COMPARATIVE-STUDIES ON PERIODATOCUPRATE(II, III) AND TELLURATOCUPRATE(II, III)

	COMPARATIVE-STUDIES ON PERIODATOCUPRATE(II, III) AND TELLURATOCUPRATE(II, III)
	WU MM ; QIANG S ; GANG H ; REN YF
刊名	journal of solid state chemistry
	1995
卷号	115 期号:1 页码:208-213
关键词	RAY PHOTOELECTRON SPECTROSCOPY X-RAY ELECTRONIC-SPECTRA COPPER(III) COMPLEXES
ISSN号	0022-4596
中文摘要	the crystal structures, electronic spectra, and cu2p xps of cu(iii) complexes na4h[cu(h2teo6)(2)]. 17h(2)o and na4k[cu(hlo(6))(2)]. 12h(2)o have been described. the characterizations of a cu(iii) atom in a complex are as follows: (i) in a square-planar coordination, the average bond length of cu-o is 0.183 nm, shorter than the 0.190-0.200 nm found for a cu(ii) complex. (2) the ''blue shift'' occurs for d-d transitions in the electronic spectrum of the cu(iii) complex compared to those of its related cu(ii) complex, resulting from the higher valence state. (3) cu(iii) compounds with cuo4 square-planar coordination are expected to be diamagnetic whereas cu(ii) compounds to be paramagnetic. (4) comprehensive investigations on cu2p xps show that the binding energy of cu2p(3/2) of a pure cu(iii) compound is about 2.0 ev higher than that of its corresponding cu(ii) compound: the shake-up satellites do not appear in the cu2p xps for a pure diamagnetic cu(iii) compound, the same as found for a diamagnetic ni(ii) compound: the fwhm of the signal of cu2p xps may become broader for cu(iii) compound because its core hole's lifetime shortens due to the higher valence state of copper. (c) 1995 academic press, inc.
收录类别	SCI收录期刊论文
语种	英语
公开日期	2010-12-30 ; 2011-06-10
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/26587]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	WU MM,QIANG S,GANG H,et al. COMPARATIVE-STUDIES ON PERIODATOCUPRATE(II, III) AND TELLURATOCUPRATE(II, III)[J]. journal of solid state chemistry,1995,115(1):208-213.
APA	WU MM,QIANG S,GANG H,&REN YF.(1995).COMPARATIVE-STUDIES ON PERIODATOCUPRATE(II, III) AND TELLURATOCUPRATE(II, III).journal of solid state chemistry,115(1),208-213.
MLA	WU MM,et al."COMPARATIVE-STUDIES ON PERIODATOCUPRATE(II, III) AND TELLURATOCUPRATE(II, III)".journal of solid state chemistry 115.1(1995):208-213.