IONIC-CONDUCTION OF A NOVEL COMB POLYMER ELECTROLYTE BASED ON MALEIC-ANHYDRIDE COPOLYMER WITH OLIGO-OXYETHYLENE SIDE-CHAINS

	IONIC-CONDUCTION OF A NOVEL COMB POLYMER ELECTROLYTE BASED ON MALEIC-ANHYDRIDE COPOLYMER WITH OLIGO-OXYETHYLENE SIDE-CHAINS
	DING LM ; LIN YQ ; YANG CZ
刊名	chemical research in chinese universities
	1995
卷号	11 期号:3 页码:243-249
关键词	COMPLEXES SALTS
ISSN号	1000-9213
中文摘要	a comb-shaped polymer (bm350) with oligo-oxyethylene side chains of the type -o(ch2ch2o)(7)ch3 was prepared from methyl vinyl ether/maleic anhydride copolymer. homogeneous amorphous polymer electrolyte complexes were made from the comb polymer and licf(3)so(3) by solvent casting from acetone, and their conductivities were measured as a function of temperature and salt concentration. maximum conductivity close to 5.08 x 10(-5) scm(-1) was obtained at room temperature and at a [li]/[eo] ratio of about 0.12. the conductivity which displayed non-arrhenius behaviour was analyzed using the vogel-tammann-fulcher equation and interpreted on the basis of the configurational entropy model. the results of mid-ir showed that the coordination of li+ to side chains made the c-o-c band become broader and shift slightly. x-ray photoelectron spectroscopy analysis indicated that the oxygen atoms in the two situations could coordinate to li+ and this coordination resulted in the reduction of the electron orbit binding energy of f and s.
收录类别	SCI收录期刊论文
语种	英语
公开日期	2010-12-30 ; 2011-06-10
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/26443]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	DING LM,LIN YQ,YANG CZ. IONIC-CONDUCTION OF A NOVEL COMB POLYMER ELECTROLYTE BASED ON MALEIC-ANHYDRIDE COPOLYMER WITH OLIGO-OXYETHYLENE SIDE-CHAINS[J]. chemical research in chinese universities,1995,11(3):243-249.
APA	DING LM,LIN YQ,&YANG CZ.(1995).IONIC-CONDUCTION OF A NOVEL COMB POLYMER ELECTROLYTE BASED ON MALEIC-ANHYDRIDE COPOLYMER WITH OLIGO-OXYETHYLENE SIDE-CHAINS.chemical research in chinese universities,11(3),243-249.
MLA	DING LM,et al."IONIC-CONDUCTION OF A NOVEL COMB POLYMER ELECTROLYTE BASED ON MALEIC-ANHYDRIDE COPOLYMER WITH OLIGO-OXYETHYLENE SIDE-CHAINS".chemical research in chinese universities 11.3(1995):243-249.