SYNTHESIS AND CHARACTERIZATION OF TRISUBSTITUTED HETEROPOLYTUNGSTOGERMANATES CONTAINING GROUP 3A ELEMENTS

	SYNTHESIS AND CHARACTERIZATION OF TRISUBSTITUTED HETEROPOLYTUNGSTOGERMANATES CONTAINING GROUP 3A ELEMENTS
	MENG L ; LIU JF
刊名	chinese journal of chemistry
	1995
卷号	13 期号:4 页码:334-339
ISSN号	1001-604x
中文摘要	six new compounds, alpha,beta-kahb[gew(9)m(3)(h2o)(3)o-37]. xh(2)o(m = al, ga, in; a + b = 7) and alpha-k9h5[ge2w18ga6(h2o)(3)o-74]. 20h(2)o, were synthesized from the lacunary precursors a and beta-gew9o3410- and characterized by elemental analysis, spectroscopy and electrochemistry. tungsten-183 nmr spectra of the title complexes consist of two lines with intensity ratio 2:1 as expected for trisubstituted heteropoly anions. the intensity ratio of alpha-ga compound is 1:2, which is different from others(a:1). with the help of fab mass spectrum, we concluded that it is a dimer with d-3h structure in aqueous, and the others exist by monomers with c-3v structures.
收录类别	SCI收录期刊论文
语种	英语
公开日期	2010-12-30 ; 2011-06-10
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/26399]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	MENG L,LIU JF. SYNTHESIS AND CHARACTERIZATION OF TRISUBSTITUTED HETEROPOLYTUNGSTOGERMANATES CONTAINING GROUP 3A ELEMENTS[J]. chinese journal of chemistry,1995,13(4):334-339.
APA	MENG L,&LIU JF.(1995).SYNTHESIS AND CHARACTERIZATION OF TRISUBSTITUTED HETEROPOLYTUNGSTOGERMANATES CONTAINING GROUP 3A ELEMENTS.chinese journal of chemistry,13(4),334-339.
MLA	MENG L,et al."SYNTHESIS AND CHARACTERIZATION OF TRISUBSTITUTED HETEROPOLYTUNGSTOGERMANATES CONTAINING GROUP 3A ELEMENTS".chinese journal of chemistry 13.4(1995):334-339.