SYNTHESIS AND CHARACTERIZATION OF TRISUBSTITUTED HETEROPOLYTUNGSTOGERMANATES CONTAINING GROUP 3A ELEMENTS | |
MENG L ; LIU JF | |
刊名 | chinese journal of chemistry
![]() |
1995 | |
卷号 | 13期号:4页码:334-339 |
ISSN号 | 1001-604x |
中文摘要 | six new compounds, alpha,beta-kahb[gew(9)m(3)(h2o)(3)o-37]. xh(2)o(m = al, ga, in; a + b = 7) and alpha-k9h5[ge2w18ga6(h2o)(3)o-74]. 20h(2)o, were synthesized from the lacunary precursors a and beta-gew9o3410- and characterized by elemental analysis, spectroscopy and electrochemistry. tungsten-183 nmr spectra of the title complexes consist of two lines with intensity ratio 2:1 as expected for trisubstituted heteropoly anions. the intensity ratio of alpha-ga compound is 1:2, which is different from others(a:1). with the help of fab mass spectrum, we concluded that it is a dimer with d-3h structure in aqueous, and the others exist by monomers with c-3v structures. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
公开日期 | 2010-12-30 ; 2011-06-10 |
内容类型 | 期刊论文 |
源URL | [http://ir.ciac.jl.cn/handle/322003/26399] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | MENG L,LIU JF. SYNTHESIS AND CHARACTERIZATION OF TRISUBSTITUTED HETEROPOLYTUNGSTOGERMANATES CONTAINING GROUP 3A ELEMENTS[J]. chinese journal of chemistry,1995,13(4):334-339. |
APA | MENG L,&LIU JF.(1995).SYNTHESIS AND CHARACTERIZATION OF TRISUBSTITUTED HETEROPOLYTUNGSTOGERMANATES CONTAINING GROUP 3A ELEMENTS.chinese journal of chemistry,13(4),334-339. |
MLA | MENG L,et al."SYNTHESIS AND CHARACTERIZATION OF TRISUBSTITUTED HETEROPOLYTUNGSTOGERMANATES CONTAINING GROUP 3A ELEMENTS".chinese journal of chemistry 13.4(1995):334-339. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论