SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE DAWSON-TYPE TUNGSTOPHOSPHATE HETEROPOLY COMPLEXES SUBSTITUTED BY NIOBIUM

	SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE DAWSON-TYPE TUNGSTOPHOSPHATE HETEROPOLY COMPLEXES SUBSTITUTED BY NIOBIUM
	QU LY ; GONG J ; WANG FQ ; CHEN YG ; ZHANG JG
刊名	acta chimica sinica
	1995
卷号	53 期号:9 页码:871-877
关键词	POLYOXOMETALATE OXIDATION CATALYSTS = MN3+ DERIVATIVES KEGGIN FE3+ CO2+ NI2+ CU2+
ISSN号	0567-7351
通讯作者	qu ly
中文摘要	eight new complexes alpha(2)-m(7-m)h(m)[p2w17nbo62]. h2o and alpha-1, 2, 3-m(g-m)h(m) [p2w15nb3o62]. xh(2)o(m=k, tma, tea, tba) were synthesized and characterized by ir and uv spectroscopy, polarography, xps and xrd methods. p-31 and w-183 nmr studies show that the niobium atoms in the anions are on the polar sites. the crystal of alpha-1, 2, 3-k7h2 [p2w15nb3o62]. 30h(2)o is hexagonal, its cell parameters: a=1.9836(4), b=1.9836(9), c=1.5498(6)nm, alpha=beta=90 degrees, gamma=120 degrees.
收录类别	SCI收录期刊论文
语种	英语
公开日期	2010-12-30 ; 2011-06-10
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/26395]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	QU LY,GONG J,WANG FQ,et al. SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE DAWSON-TYPE TUNGSTOPHOSPHATE HETEROPOLY COMPLEXES SUBSTITUTED BY NIOBIUM[J]. acta chimica sinica,1995,53(9):871-877.
APA	QU LY,GONG J,WANG FQ,CHEN YG,&ZHANG JG.(1995).SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE DAWSON-TYPE TUNGSTOPHOSPHATE HETEROPOLY COMPLEXES SUBSTITUTED BY NIOBIUM.acta chimica sinica,53(9),871-877.
MLA	QU LY,et al."SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE DAWSON-TYPE TUNGSTOPHOSPHATE HETEROPOLY COMPLEXES SUBSTITUTED BY NIOBIUM".acta chimica sinica 53.9(1995):871-877.