Barrier properties of vinylidene chloride copolymers | |
Weng ZX ; Huang ZM ; Pan ZR | |
刊名 | chinese journal of polymer science
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1996 | |
卷号 | 14期号:2页码:105-110 |
关键词 | MOLECULAR-STRUCTURE POLYMERS |
ISSN号 | 0256-7679 |
中文摘要 | the permeability coefficients of a series of copolymers of vinylidene chloride (vdc) with methyl acrylate (ma), butyl acrylate (ba) or vinyl chloride (vc) (as comonomer) to oxygen and carbon dioxide have been measured at 1.0 mpa and 30 degrees c, while those to water vapor have been measured at 30 degrees c and 100% relative humidity. all the copolymers are semicrystalline. vdc/ma copolymers have lower melting temperature compared with vdc/ba copolymers, while that melting temperature of vdc/vc copolymer is higher than that of vdc/acrylate copolymers with the same vdc content. the barrier property of the copolymers is predominantly controlled by crystallite, free volume fraction, and cohesive energy. the permeability coefficients of vdc/ma copolymers to oxygen, carbon dioxide, and water vapor were successfully correlated with the ratio of free volume to cohesive energy. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
公开日期 | 2010-12-22 ; 2011-06-09 |
内容类型 | 期刊论文 |
源URL | [http://ir.ciac.jl.cn/handle/322003/25317] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Weng ZX,Huang ZM,Pan ZR. Barrier properties of vinylidene chloride copolymers[J]. chinese journal of polymer science,1996,14(2):105-110. |
APA | Weng ZX,Huang ZM,&Pan ZR.(1996).Barrier properties of vinylidene chloride copolymers.chinese journal of polymer science,14(2),105-110. |
MLA | Weng ZX,et al."Barrier properties of vinylidene chloride copolymers".chinese journal of polymer science 14.2(1996):105-110. |
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