A study of the dependence of ferrocene diffusion on chain length in polymer electrolytes
Zhou HF ; Dong SJ
刊名journal of electroanalytical chemistry
1996
卷号414期号:2页码:121-125
关键词SOLID-STATE VOLTAMMETRY ELECTROACTIVE SOLUTES MICRODISK ELECTRODES TRANSPORT CHRONOAMPEROMETRY MICROELECTRODES COEFFICIENTS TEMPERATURE SOLVENTS FILMS
ISSN号0022-0728
中文摘要the diffusion rates of ferrocene have been estimated in five kinds of poly(ethylene glycol) solution, containing the electrolyte liclo4, by using non-steady-state chronoamperometry. the d-app of ferrocene increases with increasing temperature, and the dependency of d-app on temperature obeys the williams-landel-ferry equation. the d-app of ferrocene decreases with increasing polymer chain length. both the chain length and temperature dependence conform to a simple free volume model. a relation between current and polymer chain length is suggested at room and high temperatures.
收录类别SCI收录期刊论文
语种英语
公开日期2010-12-22 ; 2011-06-09
内容类型期刊论文
源URL[http://ir.ciac.jl.cn/handle/322003/25199]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
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GB/T 7714
Zhou HF,Dong SJ. A study of the dependence of ferrocene diffusion on chain length in polymer electrolytes[J]. journal of electroanalytical chemistry,1996,414(2):121-125.
APA Zhou HF,&Dong SJ.(1996).A study of the dependence of ferrocene diffusion on chain length in polymer electrolytes.journal of electroanalytical chemistry,414(2),121-125.
MLA Zhou HF,et al."A study of the dependence of ferrocene diffusion on chain length in polymer electrolytes".journal of electroanalytical chemistry 414.2(1996):121-125.
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