A study of the dependence of ferrocene diffusion on chain length in polymer electrolytes | |
Zhou HF ; Dong SJ | |
刊名 | journal of electroanalytical chemistry |
1996 | |
卷号 | 414期号:2页码:121-125 |
关键词 | SOLID-STATE VOLTAMMETRY ELECTROACTIVE SOLUTES MICRODISK ELECTRODES TRANSPORT CHRONOAMPEROMETRY MICROELECTRODES COEFFICIENTS TEMPERATURE SOLVENTS FILMS |
ISSN号 | 0022-0728 |
中文摘要 | the diffusion rates of ferrocene have been estimated in five kinds of poly(ethylene glycol) solution, containing the electrolyte liclo4, by using non-steady-state chronoamperometry. the d-app of ferrocene increases with increasing temperature, and the dependency of d-app on temperature obeys the williams-landel-ferry equation. the d-app of ferrocene decreases with increasing polymer chain length. both the chain length and temperature dependence conform to a simple free volume model. a relation between current and polymer chain length is suggested at room and high temperatures. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
公开日期 | 2010-12-22 ; 2011-06-09 |
内容类型 | 期刊论文 |
源URL | [http://ir.ciac.jl.cn/handle/322003/25199] |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Zhou HF,Dong SJ. A study of the dependence of ferrocene diffusion on chain length in polymer electrolytes[J]. journal of electroanalytical chemistry,1996,414(2):121-125. |
APA | Zhou HF,&Dong SJ.(1996).A study of the dependence of ferrocene diffusion on chain length in polymer electrolytes.journal of electroanalytical chemistry,414(2),121-125. |
MLA | Zhou HF,et al."A study of the dependence of ferrocene diffusion on chain length in polymer electrolytes".journal of electroanalytical chemistry 414.2(1996):121-125. |
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