Synthesis and ionic conductivity studies of solid polymer electrolytes based on modified alternating maleic anhydride copolymer with oligo(oxyethylene) side chains

	Synthesis and ionic conductivity studies of solid polymer electrolytes based on modified alternating maleic anhydride copolymer with oligo(oxyethylene) side chains
	Ding LM ; Shi J ; Ma DZ ; Dong SJ
刊名	acta polymerica
	1997
卷号	48 期号:1-2 页码:16-20
关键词	COMB POLYMERS POLY(ETHYLENE OXIDE) LITHIUM PERCHLORATE SALT MIXTURES COMPLEXES ITACONATE) TRANSPORT SILOXANE LICLO4
ISSN号	0323-7648
通讯作者	ding lm
中文摘要	comb-like polymers (cp) based on modified alternating methyl vinyl ether/maleic anhydride copolymer with oligo-oxyethylene side chains of the type-o(ch2ch2o)(n)ch3 have been synthesized and characterized, and complexed with lino3 to form an amorphous polymer electrolyte. cp/salt complexes showed conductivity up to 10(-5) s/cm at room temperature. the temperature dependence of ionic conductivity suggests that the ion transport is controlled by segmental motion of the polymer, shown by linear curves obtained in vogel-tammann-fulcher plots. the ionic conductivity maximum moves to a higher salt concentration as the temperature increases. ir results also indicate that the ester in cp might decompose at 140 degrees c and reproduce the maleic anhydride ring.
收录类别	SCI收录期刊论文
语种	英语
公开日期	2010-12-22 ; 2011-06-09
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/24405]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Ding LM,Shi J,Ma DZ,et al. Synthesis and ionic conductivity studies of solid polymer electrolytes based on modified alternating maleic anhydride copolymer with oligo(oxyethylene) side chains[J]. acta polymerica,1997,48(1-2):16-20.
APA	Ding LM,Shi J,Ma DZ,&Dong SJ.(1997).Synthesis and ionic conductivity studies of solid polymer electrolytes based on modified alternating maleic anhydride copolymer with oligo(oxyethylene) side chains.acta polymerica,48(1-2),16-20.
MLA	Ding LM,et al."Synthesis and ionic conductivity studies of solid polymer electrolytes based on modified alternating maleic anhydride copolymer with oligo(oxyethylene) side chains".acta polymerica 48.1-2(1997):16-20.