Renewable manganous hexacyanoferrate-modified graphite organosilicate composite electrode and its electrocatalytic oxidation of L-cysteine

	Renewable manganous hexacyanoferrate-modified graphite organosilicate composite electrode and its electrocatalytic oxidation of L-cysteine
	Wang P ; Jing XY ; Zhang WY ; Zhu GY
刊名	journal of solid state electrochemistry
	2001
卷号	5 期号:6 页码:369-374
关键词	MODIFIED GLASSY-CARBON SOL-GEL MATERIALS PRUSSIAN BLUE FILM COBALT-HEXACYANOFERRATE LIQUID-CHROMATOGRAPHY THIN-FILMS ELECTROCHEMISTRY POTASSIUM HYDRAZINE VOLTAMMETRY
ISSN号	1432-8488
通讯作者	zhu gy
中文摘要	manganous hexacyanoferrate (mnhcf) supported on graphite powder was dispersed into methyltrimethoxysilane-derived gels to yield a conductive composite, which was used as electrode material to construct a renewable three-dimensional mnhcf-modifed electrode. mnhcf acts as a catalyst, graphite powder ensures conductivity by percolation, the silicate provides a rigid porous backbone, and the methyl groups endow hydrophobicity and thus limit the wetting section of the modified electrode. cyclic voltammetry was exploited to investigate the dependence of electrochemical behavior on supporting electrolytes containing various cations. the chemically modified electrode can electrocatalytically oxidize l-cysteine, and exhibits a distinct advantage of polishing in the event of surface fouling, as well as simple preparation, good chemical and mechanical stability, and good repeatability of surface renewal.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000170494800001
公开日期	2010-11-04
内容类型	期刊论文
源URL	[http://202.98.16.49/handle/322003/20647]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Wang P,Jing XY,Zhang WY,et al. Renewable manganous hexacyanoferrate-modified graphite organosilicate composite electrode and its electrocatalytic oxidation of L-cysteine[J]. journal of solid state electrochemistry,2001,5(6):369-374.
APA	Wang P,Jing XY,Zhang WY,&Zhu GY.(2001).Renewable manganous hexacyanoferrate-modified graphite organosilicate composite electrode and its electrocatalytic oxidation of L-cysteine.journal of solid state electrochemistry,5(6),369-374.
MLA	Wang P,et al."Renewable manganous hexacyanoferrate-modified graphite organosilicate composite electrode and its electrocatalytic oxidation of L-cysteine".journal of solid state electrochemistry 5.6(2001):369-374.