Networks with hexagonal circuits in co-ordination polymers of metal ions (Zn-II, Cd-II) with 1,1 '-(1,4-butanediyl)bis(imidazole)

	Networks with hexagonal circuits in co-ordination polymers of metal ions (Zn-II, Cd-II) with 1,1 '-(1,4-butanediyl)bis(imidazole)
	Ma JF ; Liu JF ; Xing Y ; Jia HQ ; Lin YH
刊名	journal of the chemical society-dalton transactions
	2000
期号	14 页码:2403-2407
关键词	COORDINATION POLYMERS STRUCTURAL CHARACTERIZATION 2-DIMENSIONAL POLYROTAXANE SILVER(I) CATIONS MOLECULAR LADDERS COMPLEXES PYRAZINE SHEETS 1 INTERPENETRATION 4-BIS(IMIDAZOL-1-YLMETHYL)BENZENE
ISSN号	1470-479x
通讯作者	ma jf
中文摘要	three new compounds, [znl1.5(h2o)(so4)]. 6h(2)o 1, [znl1.5(h2o)(2)][no3](2). 2h(2)o 2 and [cdl1.5(h2o)(2)(so4)]. 4h(2)o 3 were obtained from self-assembly of the corresponding metal salts with 1,1'-(1,4-butanediyl)bis(imidazole) (l). in both 1 and 2 zinc ion is five-co-ordinated, showing a less-common trigonal bipyramidal co-ordination polyhedron, while cadmium ion of 3 is six-co-ordinated with a common octahedral arrangement. the sulfate ions of 1 and 3 are co-ordinated, however the nitrate ions of 2 are not. each of the three compounds is composed of a (6, 3) network with the hexagonal smallest circuit containing six metal ions and six l; each l is co-ordinated to two metal ions, acting as a bridging ligand. in 1 the 2-d sheet of (6, 3) networks is interpenetrated in an inclined mode by symmetry related, identical sheets to give an interlocked 3-d structure, while the (6, 3) networks of both 2 and 3 stack in a parallel fashion to construct frameworks having channels.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000088758800025
公开日期	2010-11-04
内容类型	期刊论文
源URL	[http://202.98.16.49/handle/322003/19639]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Ma JF,Liu JF,Xing Y,et al. Networks with hexagonal circuits in co-ordination polymers of metal ions (Zn-II, Cd-II) with 1,1 '-(1,4-butanediyl)bis(imidazole)[J]. journal of the chemical society-dalton transactions,2000(14):2403-2407.
APA	Ma JF,Liu JF,Xing Y,Jia HQ,&Lin YH.(2000).Networks with hexagonal circuits in co-ordination polymers of metal ions (Zn-II, Cd-II) with 1,1 '-(1,4-butanediyl)bis(imidazole).journal of the chemical society-dalton transactions(14),2403-2407.
MLA	Ma JF,et al."Networks with hexagonal circuits in co-ordination polymers of metal ions (Zn-II, Cd-II) with 1,1 '-(1,4-butanediyl)bis(imidazole)".journal of the chemical society-dalton transactions .14(2000):2403-2407.