Preparation, characterization and photophysical properties of layered zirconium bis(monohydrogenphosphate) intercalated with rare earth complexes

	Preparation, characterization and photophysical properties of layered zirconium bis(monohydrogenphosphate) intercalated with rare earth complexes
	Xu QH ; Fu LS ; Li LS ; Zhang HJ ; Xu RR
刊名	journal of materials chemistry
	2000
卷号	10 期号:11 页码:2532-2536
关键词	PHOTOINDUCED CHARGE SEPARATION ION-EXCHANGE PHOSPHATE LUMINESCENCE DYES
ISSN号	0959-9428
通讯作者	xu rr
中文摘要	two kinds of rare earth (re) complexes were intercalated into zirconium bis(monohydrogenphosphate) (alpha -zrp) by exchanging the re complexes into the p-methyoxyaniline (pma) preintercalated compound zr(o3poh)(2). 2pma (alpha -zrp . 2pma). powder x-ray diffraction patterns reveal that eu(dbm)(3)phen (dbm: dibenzoylmethane, phen: 1,10-phenanthroline) and tb(aa)(3)phen (aa: acetylacetone) intercalated into alpha -zrp . 2pma. this was confirmed by the uv-visible spectra of both the re complexes and the assemblies. at the same time, the assemblies have better luminescent properties, and the fluorescent lifetimes of re3+ in the excited state in the assemblies are much longer than those in the complexes. the stabilities of the assemblies under uv radiation are much better than those of the re complexes.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000090052000019
公开日期	2010-11-04
内容类型	期刊论文
源URL	[http://202.98.16.49/handle/322003/19507]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Xu QH,Fu LS,Li LS,et al. Preparation, characterization and photophysical properties of layered zirconium bis(monohydrogenphosphate) intercalated with rare earth complexes[J]. journal of materials chemistry,2000,10(11):2532-2536.
APA	Xu QH,Fu LS,Li LS,Zhang HJ,&Xu RR.(2000).Preparation, characterization and photophysical properties of layered zirconium bis(monohydrogenphosphate) intercalated with rare earth complexes.journal of materials chemistry,10(11),2532-2536.
MLA	Xu QH,et al."Preparation, characterization and photophysical properties of layered zirconium bis(monohydrogenphosphate) intercalated with rare earth complexes".journal of materials chemistry 10.11(2000):2532-2536.