A highly reduced polyoxoanion with phosphorus-centered alternate layers of Mo/V oxides, [(PMo2Mo6V4O40)-Mo-V-V-VI-O-IV((VO)-O-IV)(2)](9-)

	A highly reduced polyoxoanion with phosphorus-centered alternate layers of Mo/V oxides, [(PMo2Mo6V4O40)-Mo-V-V-VI-O-IV((VO)-O-IV)(2)](9-)
	Li YG ; Wang EB ; Wang ST ; Duan YB ; Hu CW ; Hu NH ; Jia HQ
刊名	journal of molecular structure
	2002
卷号	611 期号:1-3 页码:185-191
关键词	CRYSTAL-STRUCTURE HYDROTHERMAL SYNTHESIS X-RAY
ISSN号	0022-2860
通讯作者	wang eb
中文摘要	an unusual polyoxometalate [h2n(c2h4)(2)nh2](4)(h3o)[(pmo2mo6v4o40)-mo-v-v-vi-o-iv((vo)-o-iv)(2)].h2o is hydrothermally synthesized and characterized by ir, uv-vis, elemental analyses, x-ray photoelectron spectrum, esr, tg and single crystal x-ray diffraction. the title compound crystallizes in the orthorhombic space group pbca with a = 15-227(5), b = 19.491(4), c = 18.737(3) angstrom, v = 5123(2) angstrom(3), z = 4, and r-1 (wr(2)) = 0.0726(0.1416). the compound contains an unusual highly reduced pseudo-keggin type polyoxoanion and exhibits an interesting phosphorus-centered alternate arrangement of layers of molybdenum and vanadium oxides.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000176144400020
公开日期	2010-11-03
内容类型	期刊论文
源URL	[http://202.98.16.49/handle/322003/18525]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Li YG,Wang EB,Wang ST,et al. A highly reduced polyoxoanion with phosphorus-centered alternate layers of Mo/V oxides, [(PMo2Mo6V4O40)-Mo-V-V-VI-O-IV((VO)-O-IV)(2)](9-)[J]. journal of molecular structure,2002,611(1-3):185-191.
APA	Li YG.,Wang EB.,Wang ST.,Duan YB.,Hu CW.,...&Jia HQ.(2002).A highly reduced polyoxoanion with phosphorus-centered alternate layers of Mo/V oxides, [(PMo2Mo6V4O40)-Mo-V-V-VI-O-IV((VO)-O-IV)(2)](9-).journal of molecular structure,611(1-3),185-191.
MLA	Li YG,et al."A highly reduced polyoxoanion with phosphorus-centered alternate layers of Mo/V oxides, [(PMo2Mo6V4O40)-Mo-V-V-VI-O-IV((VO)-O-IV)(2)](9-)".journal of molecular structure 611.1-3(2002):185-191.