Electrochemiluminescent determination of glucose with a sol-gel derived ceramic-carbon composite electrode as a renewable optical fiber biosensor
Zhu LD ; Li YX ; Tian FM ; Xu B ; Zhu GY
刊名sensors and actuators b-chemical
2002
卷号84期号:2-3页码:265-270
关键词ELECTROGENERATED CHEMILUMINESCENCE LUMINOL ELECTROCHEMILUMINESCENCE NATURAL SAMPLES OXIDASE LAYER
ISSN号0925-4005
通讯作者zhu ld
中文摘要a sol-gel derived ceramic-carbon composite electrode is used for fabrication of a new type of optical fiber biosensor based on luminol electrochemiluminescence (ecl). the electrode consists of graphite powder impregnated with glucose oxidase in a silicate network. in this configuration, the immobilized enzyme oxidizes glucose to liberate hydrogen peroxide and graphite powder provides percolation conductivity for triggering the ecl between luminol and the liberated hydrogen peroxide. both of the reactions occur simultaneously on the surface of the composite electrode, thereby the response of the biosensor is very fast. the peak intensity was achieved within only 20 s after glucose injection. in addition, the electrode could be renewed by a simple mechanical polishing step in case of contamination or fouling. the linear range extends from 0.01 to 10 mm for glucose and the detection limit is about 8.16 mum. the renewal repeatability and stability of the biosensor are also investigated in detail.
收录类别SCI收录期刊论文
语种英语
WOS记录号WOS:000176345900025
公开日期2010-11-03
内容类型期刊论文
源URL[http://202.98.16.49/handle/322003/18497]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
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GB/T 7714
Zhu LD,Li YX,Tian FM,et al. Electrochemiluminescent determination of glucose with a sol-gel derived ceramic-carbon composite electrode as a renewable optical fiber biosensor[J]. sensors and actuators b-chemical,2002,84(2-3):265-270.
APA Zhu LD,Li YX,Tian FM,Xu B,&Zhu GY.(2002).Electrochemiluminescent determination of glucose with a sol-gel derived ceramic-carbon composite electrode as a renewable optical fiber biosensor.sensors and actuators b-chemical,84(2-3),265-270.
MLA Zhu LD,et al."Electrochemiluminescent determination of glucose with a sol-gel derived ceramic-carbon composite electrode as a renewable optical fiber biosensor".sensors and actuators b-chemical 84.2-3(2002):265-270.
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