Hydrothermal synthesis and crystal structure of a hybrid material based on [Co-4(phen)(8)(H2O)(2)(HPO3)(2)](4+) and a highly reduced polyoxoanion

	Hydrothermal synthesis and crystal structure of a hybrid material based on [Co-4(phen)(8)(H2O)(2)(HPO3)(2)](4+) and a highly reduced polyoxoanion
	Yuan M ; Li YG ; Wang E ; Lu Y ; Hu CW ; Hu NH ; Jia HQ
刊名	journal of the chemical society-dalton transactions
	2002
期号	14 页码:2916-2920
关键词	STATE COORDINATION CHEMISTRY CHARGE-TRANSFER SALTS MAGNETIC-PROPERTIES WATER-MOLECULES X-RAY CLUSTERS CHAINS CO NI
ISSN号	1472-7773
通讯作者	wang e
中文摘要	an unusual composite hybrid material [co-4 (phen)(8) (h2o)(2) (hpo3)(2)](h3o)(3) [pmo8vi v-4(iv) o-40 ((vo)-o-iv) 2] 1 (phen = 1,10-phenanthroline) has been hydrothermally synthesized from a mixture of nh4vo3, na2moo4.2h(2)o, cocl2.6h(2)o, phen, h3po3 and water. it was characterized by elemental analysis, ir, uv-vis, xps, epr, tg and single crystal x-ray diffraction. the title compound is constructed from the organic-inorganic hybrid [co-4(phen)(8)(h2o)(2) (hpo3)(2)](4+) and highly reduced bi-capped pseudo-keggin [(pmo8v4o40)-v-vi-o-iv ((vo)-o-iv)(2)](7-) polyoxoanions the structure exhibits an extended 2d network through hydrogen bonds among cations, anions and h2o, combining polyoxometalates with metal phosphonates for the first time.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000176822000024
公开日期	2010-11-03
内容类型	期刊论文
源URL	[http://202.98.16.49/handle/322003/18455]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Yuan M,Li YG,Wang E,et al. Hydrothermal synthesis and crystal structure of a hybrid material based on [Co-4(phen)(8)(H2O)(2)(HPO3)(2)](4+) and a highly reduced polyoxoanion[J]. journal of the chemical society-dalton transactions,2002(14):2916-2920.
APA	Yuan M.,Li YG.,Wang E.,Lu Y.,Hu CW.,...&Jia HQ.(2002).Hydrothermal synthesis and crystal structure of a hybrid material based on [Co-4(phen)(8)(H2O)(2)(HPO3)(2)](4+) and a highly reduced polyoxoanion.journal of the chemical society-dalton transactions(14),2916-2920.
MLA	Yuan M,et al."Hydrothermal synthesis and crystal structure of a hybrid material based on [Co-4(phen)(8)(H2O)(2)(HPO3)(2)](4+) and a highly reduced polyoxoanion".journal of the chemical society-dalton transactions .14(2002):2916-2920.