Charge transfer across the water/nitrobenzene interface by three-electrode system

	Charge transfer across the water/nitrobenzene interface by three-electrode system
	Yuan Y ; Gao Z ; Zhang MQ ; Zhang ZQ ; Shao YH
刊名	science in china series b-chemistry
	2002
卷号	45 期号:5 页码:494-502
关键词	ION TRANSFER-REACTIONS LIQUID INTERFACE LIQUID/LIQUID INTERFACES NITROBENZENE VOLTAMMETRY WATER
ISSN号	1006-9291
通讯作者	yuan y
中文摘要	a droplet of aqueous solution containing a certain molar ratio of redox couple is first attached onto a platinum electrode surface, then the resulting drop electrode is immersed into the organic solution containing very hydrophobic electrolyte. combined with reference and counter electrodes, a classical three-electrode system has been constructed, ion transfer (it) and electron transfer (et) are investigated systematically using three-electrode voltammetry. potassium ion transfer and electron transfer between potassium ferricyanide in the aqueous phase and ferrocene in nitrobenzene are observed with potassium ferricyanide/potassium ferrocyanide as the redox couple. meanwhile, the transfer reactions of lithium, sodium, potassium, proton and ammonium ions are obtained with ferric sulfate/ferrous sulfate as the redox couple. the formal transfer potentials and the standard gibbs transfer energy of these ions are evaluated and consistent with the results obtained by a four-electrode system and other methods.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000178162500008
公开日期	2010-11-03
内容类型	期刊论文
源URL	[http://202.98.16.49/handle/322003/18315]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Yuan Y,Gao Z,Zhang MQ,et al. Charge transfer across the water/nitrobenzene interface by three-electrode system[J]. science in china series b-chemistry,2002,45(5):494-502.
APA	Yuan Y,Gao Z,Zhang MQ,Zhang ZQ,&Shao YH.(2002).Charge transfer across the water/nitrobenzene interface by three-electrode system.science in china series b-chemistry,45(5),494-502.
MLA	Yuan Y,et al."Charge transfer across the water/nitrobenzene interface by three-electrode system".science in china series b-chemistry 45.5(2002):494-502.