Syntheses and crystal structures of bis(tetrahydrofurfurylindenyl) lanthanocene chlorides (C4H7OCH2C9H6)(2)LnCl (Ln = Nd, Sm, Dy, Ho, Er, Yb)

	Syntheses and crystal structures of bis(tetrahydrofurfurylindenyl) lanthanocene chlorides (C4H7OCH2C9H6)(2)LnCl (Ln = Nd, Sm, Dy, Ho, Er, Yb)
	Cheng JH ; Cui DM ; Chen WQ ; Tang T ; Huang BT
刊名	journal of organometallic chemistry
	2002
卷号	658 期号:1-2 页码:153-158
关键词	ORGANOLANTHANIDE-CATALYZED HYDROAMINATION HIGHLY REACTIVE ORGANOLANTHANIDES ZIEGLER-NATTA POLYMERIZATION UNPROTECTED AMINO OLEFINS CYCLOPENTADIENYL COMPOUNDS SIDE-CHAIN R = COMPLEXES CHEMISTRY LIGANDS
ISSN号	0022-328x
通讯作者	tang t
中文摘要	reaction of anhydrous lanthanide trichlorides with tetrahydrofurfuryl indenyl lithium in thf afforded bis(tetrahydrofurfurylindenyl) lanthanocene chlorides complexes (c4h7och2c9h6)(2) lncl, ln = nd (1), sm (2), dy (3), ho (4), er (5), yb (6). the x-ray crystallographic structures of all the six complexes were determined and these indicate that they are unsolvated nine-coordinate monomeric complexes with a trans arrangement of both the sidearm and indenyl rings in the solid state. they belong to the same crystal system (orthorhombic) and space group (p2(1)2(1)2(1)) with the same structure. especially, they are more stable to air and moisture than the corresponding unsubstituted indenyl lanthanide complexes.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000178258500019
公开日期	2010-11-03
内容类型	期刊论文
源URL	[http://202.98.16.49/handle/322003/18307]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Cheng JH,Cui DM,Chen WQ,et al. Syntheses and crystal structures of bis(tetrahydrofurfurylindenyl) lanthanocene chlorides (C4H7OCH2C9H6)(2)LnCl (Ln = Nd, Sm, Dy, Ho, Er, Yb)[J]. journal of organometallic chemistry,2002,658(1-2):153-158.
APA	Cheng JH,Cui DM,Chen WQ,Tang T,&Huang BT.(2002).Syntheses and crystal structures of bis(tetrahydrofurfurylindenyl) lanthanocene chlorides (C4H7OCH2C9H6)(2)LnCl (Ln = Nd, Sm, Dy, Ho, Er, Yb).journal of organometallic chemistry,658(1-2),153-158.
MLA	Cheng JH,et al."Syntheses and crystal structures of bis(tetrahydrofurfurylindenyl) lanthanocene chlorides (C4H7OCH2C9H6)(2)LnCl (Ln = Nd, Sm, Dy, Ho, Er, Yb)".journal of organometallic chemistry 658.1-2(2002):153-158.