Novel two-dimensional sodium molybdenum phosphates containing {M(enMe)(2)}(2+) bridging groups (M = Ni, Cu; enMe=1,2-diaminopropane) | |
Huang RD ; Liu FC ; Li YG ; Yuan M ; Wang EB ; DE GH ; Hu CW ; Hu NH ; Jia HQ | |
刊名 | inorganica chimica acta |
2003 | |
卷号 | 349页码:85-90 |
关键词 | HYDROTHERMAL SYNTHESIS POLYMER TUNNEL |
ISSN号 | 0020-1693 |
通讯作者 | wang eb |
中文摘要 | two novel organic-inorganic hybrid compounds, (h(2)enme)(4)(h3o)[ni(enme)(2)].[na3mo12o52p8(oh)(10)].5h(2)o (1) and (h(2)enme)(4)(h3o)[cu(enme)(2)].[na3mo12o52p8(oh)(10)].5h(2)o (2) (enme = 1,2-diaminopropane), have been hydrothermally synthesized and characterized by elemental analyses, ir, epr, xps, uv-vis spectra and tg analyses. single crystal x-ray diffraction shows that 1 and 2 are isostructural compounds. both the compounds exhibit an unusual two-dimensional (2-d) window-like network consisting of one-dimensional (1-d) chains of sodium molybdenum phosphate anions connected by transition metal coordination complexes cations. compound 1 and 2 represent the first 2-d molybdenum phosphate skeleton pillared by transition metal complex fragments. |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000183673100012 |
公开日期 | 2010-09-13 |
内容类型 | 期刊论文 |
源URL | [http://202.98.16.49/handle/322003/17571] |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Huang RD,Liu FC,Li YG,et al. Novel two-dimensional sodium molybdenum phosphates containing {M(enMe)(2)}(2+) bridging groups (M = Ni, Cu; enMe=1,2-diaminopropane)[J]. inorganica chimica acta,2003,349:85-90. |
APA | Huang RD.,Liu FC.,Li YG.,Yuan M.,Wang EB.,...&Jia HQ.(2003).Novel two-dimensional sodium molybdenum phosphates containing {M(enMe)(2)}(2+) bridging groups (M = Ni, Cu; enMe=1,2-diaminopropane).inorganica chimica acta,349,85-90. |
MLA | Huang RD,et al."Novel two-dimensional sodium molybdenum phosphates containing {M(enMe)(2)}(2+) bridging groups (M = Ni, Cu; enMe=1,2-diaminopropane)".inorganica chimica acta 349(2003):85-90. |
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