Modified polyoxometalates: Hydrothermal syntheses and crystal structures of three novel reduced and capped Keggin derivatives decorated by transition metal complexes

	Modified polyoxometalates: Hydrothermal syntheses and crystal structures of three novel reduced and capped Keggin derivatives decorated by transition metal complexes
	Yuan M ; Li YG ; Wang EB ; Tian CG ; Wang L ; Hu CW ; Hu NH ; Jia HQ
刊名	inorganic chemistry
	2003
卷号	42 期号:11 页码:3670-3676
关键词	COORDINATED WATER-MOLECULES LIGAND INFLUENCES BUILDING-BLOCKS ANIONS HETEROPOLYVANADATE POLYOXOANION PHOSPHATE MAGNETISM NETWORKS CLUSTERS
ISSN号	0020-1669
通讯作者	wang eb
中文摘要	three novel polyoxometalate derivatives decorated by transition metal complexes have been hydrothermally synthesized. compound 1 consists of [(pmo6mo2v8o44)-mo-vi-v-v-o-iv{co (2,2'-bipy)(2)(h2o)}(4)](3+) polyoxocations and [(pmo4mo4v8o44)-mo-iv-v-v-o-iv{co(2,2'-bipy)(2)(h2o)}(2)](3-) polyoxoanions, which are both built on mixed-metal tetracapped [pmo8v8o44] subunits covalently bonded to four or two {co(2,2'-bpy)(2)(h2o)}(2+), clusters via terminal oxo groups of the capping v atoms. compound 2 is built on [(pmo8v6o42)-v-vi-o-iv{cu-i(phen)}(2)](5-) clusters constructed from mixed-metal bicapped [(pmo8v6o42)-v-vi-o-iv](7-) subunits covalently bonded to two {cu(phen)}(+) fragments in the similar way to 1. the structure of 3 is composed of [(pmo9mo3o40)-mo-vi-o-v](6-) units capped by two divalent ni atoms via four bridging oxo groups.
收录类别	SCI
语种	英语
WOS记录号	WOS:000183222100040
公开日期	2010-09-13
内容类型	期刊论文
源URL	[http://202.98.16.49/handle/322003/17395]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Yuan M,Li YG,Wang EB,et al. Modified polyoxometalates: Hydrothermal syntheses and crystal structures of three novel reduced and capped Keggin derivatives decorated by transition metal complexes[J]. inorganic chemistry,2003,42(11):3670-3676.
APA	Yuan M.,Li YG.,Wang EB.,Tian CG.,Wang L.,...&Jia HQ.(2003).Modified polyoxometalates: Hydrothermal syntheses and crystal structures of three novel reduced and capped Keggin derivatives decorated by transition metal complexes.inorganic chemistry,42(11),3670-3676.
MLA	Yuan M,et al."Modified polyoxometalates: Hydrothermal syntheses and crystal structures of three novel reduced and capped Keggin derivatives decorated by transition metal complexes".inorganic chemistry 42.11(2003):3670-3676.