Self-assembled monolayer growth of octanol on mica: Atomic force microscopy and Fourier-transform infrared spectroscopy studies
Wang L ; Jiang JG ; Song YH ; Zhang BL ; Wang EK
刊名langmuir
2003
卷号19期号:12页码:4953-4957
关键词SCANNING-TUNNELING-MICROSCOPY LIQUID GRAPHITE INTERFACE LANGMUIR-BLODGETT-FILMS MOLECULAR-DYNAMICS LIPID MONOLAYERS FATTY-ACIDS N-ALKANE IMAGE-CONTRAST PHASE-BEHAVIOR DNA
ISSN号0743-7463
通讯作者wang ek
中文摘要the growth kinetics of self-assembled monolayers formed by exposing freshly cleaved mica to octanol solution has been studied by atomic force microscopy (afm) and fourier-transform infrared spectroscopy (ftir). afm images of samples immersed in octanol for varying exposure times showed that before forming a complete monolayer the octanol molecules aggregated in the form of small islands on the mica surface. with the proceeding of immersion, these islands gradually grew and merged into larger patches. finally, a close-packed film with uniform appearance and few defects was formed. the thickness of the final film showed 0.8 nm in height, which corresponded to the 40degrees tilt molecular conformation of the octanol monolayer. the growth mechanisms consisted of nucleation, growth, and coalescence of the submonolayer films. the growth process was also confirmed by ftir. and the surface coverage of the submonolayer islands estimated from afm images and ftir spectra as a function of immersion time was quite consistent.
收录类别SCI
语种英语
WOS记录号WOS:000183410400014
公开日期2010-09-13
内容类型期刊论文
源URL[http://202.98.16.49/handle/322003/17187]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
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GB/T 7714
Wang L,Jiang JG,Song YH,et al. Self-assembled monolayer growth of octanol on mica: Atomic force microscopy and Fourier-transform infrared spectroscopy studies[J]. langmuir,2003,19(12):4953-4957.
APA Wang L,Jiang JG,Song YH,Zhang BL,&Wang EK.(2003).Self-assembled monolayer growth of octanol on mica: Atomic force microscopy and Fourier-transform infrared spectroscopy studies.langmuir,19(12),4953-4957.
MLA Wang L,et al."Self-assembled monolayer growth of octanol on mica: Atomic force microscopy and Fourier-transform infrared spectroscopy studies".langmuir 19.12(2003):4953-4957.
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