Electron effect of p-substituent on iron(II) and cobalt(II) pyridinebisimine catalyst for ethylene polymerization

	Electron effect of p-substituent on iron(II) and cobalt(II) pyridinebisimine catalyst for ethylene polymerization
	Liu JY ; Zheng Y ; Hu NH ; Li YS
刊名	chinese journal of chemistry
	2006
卷号	24 期号:10 页码:1447-1451
关键词	TRANSITION-METAL-COMPLEXES 2 OLEFIN POLYMERIZATION ALPHA-OLEFINS OLIGOMERIZATION COPOLYMERIZATION 6-BIS(IMINO)PYRIDYL IRON
ISSN号	1001-604x
通讯作者	liu jy
中文摘要	a series of 2,6-bis(imino)pyridyl iron and cobalt complexes bearing p-substituent [2,6-(arn=cme)(2)c5h3n]-mcl2 (ar=2,6-me2c6h3, 2,4,6-me3c6h2, 2,6-me-2-4-brc6h2, 2,6-me-2-4-clc6h2, 2,4-me-2-6-brc6h2, 2,4-me-(2)-6-clc6h2, while m=fe, co) have been synthesized and investigated as catalysts for ethylene polymerization in the presence of modified methylaluminoxane as a cocatalyst. the electron effect and positions of the substitueni of pyridinebisimine ligands were observed to affect considerably catalyst activity and polymer property.
收录类别	SCI
语种	英语
WOS记录号	WOS:000241082900036
公开日期	2010-08-17
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/16779]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Liu JY,Zheng Y,Hu NH,et al. Electron effect of p-substituent on iron(II) and cobalt(II) pyridinebisimine catalyst for ethylene polymerization[J]. chinese journal of chemistry,2006,24(10):1447-1451.
APA	Liu JY,Zheng Y,Hu NH,&Li YS.(2006).Electron effect of p-substituent on iron(II) and cobalt(II) pyridinebisimine catalyst for ethylene polymerization.chinese journal of chemistry,24(10),1447-1451.
MLA	Liu JY,et al."Electron effect of p-substituent on iron(II) and cobalt(II) pyridinebisimine catalyst for ethylene polymerization".chinese journal of chemistry 24.10(2006):1447-1451.