Synthesis, crystal structure and magnetic properties of a chain coordination polymer {[Cu4L2(H2O)] center dot H2O}(n)

	Synthesis, crystal structure and magnetic properties of a chain coordination polymer {[Cu4L2(H2O)] center dot H2O}(n)
	Tao RJ ; Li FA ; Cheng YX ; Zang SQ ; Wang QL ; Niu JY ; Liao DZ
刊名	inorganica chimica acta
	2006
卷号	359 期号:7 页码:2053-2058
关键词	TETRANUCLEAR COMPLEXES LIGANDS HEXAFLUOROACETYLACETONE INTERPENETRATION ARCHITECTURES MONONUCLEAR COPPER(II) ANISOTROPY OXIDATION MOLECULE
ISSN号	0020-1693
通讯作者	tao rj
中文摘要	a chain coordination polymer with the chemical formula {[cu4l2(h2o)] (.) h2o)(n), has been synthesized by the assembly reaction of k(2)cul(.)1.5h(2)o and cu(oac)(2)(h2o)-h-. with a 1:1 mole ratio in methanol., where h4l=2-hydroxy-3-[(e)-({2-[(2-hydroxybenzoyl)imino]ethyl i imino)methyl] benzoic acid, oac(-) = ch3coo-. the crystal structure was determined by single-crystal x-ray diffraction analysis, the compound has chain molecular structure formed by dissymmetrical tetranuclear units. the magnetic measurements showed that cu-cu of the complex exhibit antiferromagnetic interactions, and satisfactory fittings to the observed magnetic susceptibility data were obtained by assuming a binuclear system, and further using molecular field approximation to deal with magnetic exchange interactions between binuclear systems.
收录类别	SCI
语种	英语
WOS记录号	WOS:000236960800009
公开日期	2010-08-17
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/16511]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Tao RJ,Li FA,Cheng YX,et al. Synthesis, crystal structure and magnetic properties of a chain coordination polymer {[Cu4L2(H2O)] center dot H2O}(n)[J]. inorganica chimica acta,2006,359(7):2053-2058.
APA	Tao RJ.,Li FA.,Cheng YX.,Zang SQ.,Wang QL.,...&Liao DZ.(2006).Synthesis, crystal structure and magnetic properties of a chain coordination polymer {[Cu4L2(H2O)] center dot H2O}(n).inorganica chimica acta,359(7),2053-2058.
MLA	Tao RJ,et al."Synthesis, crystal structure and magnetic properties of a chain coordination polymer {[Cu4L2(H2O)] center dot H2O}(n)".inorganica chimica acta 359.7(2006):2053-2058.