MANNICH-TYPE REACTION FOR SYNTHESIS OF 3-METHYL-4-NITROIMINO-TETRAHYDRO-1,3,5-OXADIAZINE

doi:10.1080/00397911.2010.550705

CORC > 中国农业科学院 > 植物保护研究所

	MANNICH-TYPE REACTION FOR SYNTHESIS OF 3-METHYL-4-NITROIMINO-TETRAHYDRO-1,3,5-OXADIAZINE
	Qu, Wen-Yan; She, Dong-Mei; Zhao, Jian; Lin, De-Jie; Huang, Qi-Liang; Li, Feng-Min
刊名	SYNTHETIC COMMUNICATIONS
	2012
卷号	42 期号:13 页码:1950-1958
关键词	Formaldehyde Mannich reaction 3-methyl-4-nitroimino-tetrahydro-1,3,5-oxadiazine N-(1,5-dimethyl-1,3,5-triazinan-2-ylidene)nitramide N-(5-ethyl-1-methyl-1,3,5-triazinan-2-ylidene)nitramide N-methyl-N '-nitroguanidine
ISSN号	0039-7911
DOI	10.1080/00397911.2010.550705
通讯作者	Qu, Wen-Yan
英文摘要	The reaction of N-methyl-N'-nitroguanidine with 3-methyl-4-nitroiminotetrahydro-1,3,5-oxadiazine is a Mannich-type reaction. The reaction was catalyzed by several organic and inorganic bases at different reaction times and temperatures. Three inorganic base catalysts [potassium carbonate (K2CO3), sodium hydrogen carbonate (NaHCO3), and sodium hydroxide (NaOH)] and several organic bases (methylamine, ethamine, iso-propylamine, and n-butylamine) have been studied. The results showed that both the inorganic and organic base catalysts can be used as catalysts, with the organic bases performing better. N-Methyl-N'-nitroguanidine reacts to give the title compound 2 and is catalyzed by both acids and bases. The intensity of inorganic base catalysts, reaction temperature, and reaction time had significant effects on the products.
学科主题	Chemistry, Organic ; CHEMISTRY, ORGANIC
语种	英语
出版者	TAYLOR & FRANCIS INC
WOS记录号	WOS:000304323100010
内容类型	期刊论文
源URL	[http://111.203.20.206/handle/2HMLN22E/12300]
专题	植物保护研究所
作者单位	Chinese Acad Agr Sci, Inst Plant Protect, Key Lab Pesticide Chem & Applicat, MOA, Beijing 100193, Peoples R China
推荐引用方式 GB/T 7714	Qu, Wen-Yan,She, Dong-Mei,Zhao, Jian,et al. MANNICH-TYPE REACTION FOR SYNTHESIS OF 3-METHYL-4-NITROIMINO-TETRAHYDRO-1,3,5-OXADIAZINE[J]. SYNTHETIC COMMUNICATIONS,2012,42(13):1950-1958.
APA	Qu, Wen-Yan,She, Dong-Mei,Zhao, Jian,Lin, De-Jie,Huang, Qi-Liang,&Li, Feng-Min.(2012).MANNICH-TYPE REACTION FOR SYNTHESIS OF 3-METHYL-4-NITROIMINO-TETRAHYDRO-1,3,5-OXADIAZINE.SYNTHETIC COMMUNICATIONS,42(13),1950-1958.
MLA	Qu, Wen-Yan,et al."MANNICH-TYPE REACTION FOR SYNTHESIS OF 3-METHYL-4-NITROIMINO-TETRAHYDRO-1,3,5-OXADIAZINE".SYNTHETIC COMMUNICATIONS 42.13(2012):1950-1958.