Crystallization kinetics and morphology of nylon 1212
Ren MQ ; Mo ZS ; Chen QY ; Song JB ; Wang SY ; Zhang HF ; Zhao QX
刊名polymer
2004
卷号45期号:10页码:3511-3518
关键词FOLDED LAMELLAR CRYSTALS POLY(ETHER ETHER KETONE) EVEN-EVEN NYLONS NONISOTHERMAL CRYSTALLIZATION SPHERULITIC CRYSTALLIZATION GROWTH-RATES POLYPROPYLENE MELT NUCLEATION POLYAMIDES
ISSN号0032-3861
通讯作者mo zs
中文摘要the isothermal and non-isothermal crystallization processes of nylon 1212 were investigated by polarized optical microscopy. the crystal growth rates of nylon 1212 measured in isothermal conditions at temperatures ranged from 182 to 132 degreesc are well comparable with those measured by non-isothermal procedures (cooling rates ranged from 0.5 to 11 degreesc/min). the kinetic data were examined with the hoffman-lauritzen nucleation theory on the basis of the obtained values of the thermodynamic parameters of nylon 1212. the classical regime i --> ii and regime ii --> iii transitions occur at the temperatures of 179 and 159 degreesc, respectively. the crystal growth parameters were calculated with (100) plane assumed to be the growth plane. the regime i --> ii --> iii transition is accompanied by a morphological transition from elliptical-shaped structure to banded spherulite and then non-banded spherulite. the development of morphology during isothermal and non-isothermal processes shows a good agreement.
收录类别SCI
语种英语
WOS记录号WOS:000221135800044
公开日期2010-08-17
内容类型期刊论文
源URL[http://202.98.16.49/handle/322003/14875]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
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GB/T 7714
Ren MQ,Mo ZS,Chen QY,et al. Crystallization kinetics and morphology of nylon 1212[J]. polymer,2004,45(10):3511-3518.
APA Ren MQ.,Mo ZS.,Chen QY.,Song JB.,Wang SY.,...&Zhao QX.(2004).Crystallization kinetics and morphology of nylon 1212.polymer,45(10),3511-3518.
MLA Ren MQ,et al."Crystallization kinetics and morphology of nylon 1212".polymer 45.10(2004):3511-3518.
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