Electrosynthesis and characterization of 1,2-dibenzyl C-60: A revisit

	Electrosynthesis and characterization of 1,2-dibenzyl C-60: A revisit
	Zheng M ; Li FF ; Shi ZJ ; Gao X ; Kadish KM
刊名	journal of organic chemistry
	2007
卷号	72 期号:7 页码:2538-2542
关键词	ELECTRON-TRANSFER FULLERENE DERIVATIVES CHEMICAL GENERATION ALKYL BROMIDES CHEMISTRY ELECTROCHEMISTRY ADDUCTS BUCKMINSTERFULLERENES ISOMERS REDOX
ISSN号	0022-3263
通讯作者	gao x
中文摘要	a reinvestigation of the reaction between c-60(2-) and benzyl bromide in benzonitrile containing 0.1 m tetra-n-butylammonium perchlorate (tbap) has shown that there are more reaction products than previously reported. use of a silica rather than a "buckyclutcher i" column for hplc purification led to isolation of two previously unattained products in the reaction mixture, one of which was identified as 1,2-(phch2)(2)c-60 by uv-vis and nmr. the earlier incorrectly assigned 1,2-(phch2)(2)c-60 was identified as the methanofullerene c61hph by x-ray single-crystal diffraction. the electrochemistry of genuine 1,2-(phch2)(2)c-60 shows that its first reduction potential in phcn containing 0.1 m tbap is cathodically shifted by 100 mv with respect to e-1/2 for reduction of 1,4-(phch2)(2)c-60, indicating that the addition pattern significantly affects the electrochemistry of derivatized c-60. visible and near-ir spectra of the monoanion and dianion of 1,2-(phch2)(2)c-60 are also reported.
收录类别	SCI
语种	英语
WOS记录号	WOS:000245118900035
公开日期	2010-07-13
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/14633]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Zheng M,Li FF,Shi ZJ,et al. Electrosynthesis and characterization of 1,2-dibenzyl C-60: A revisit[J]. journal of organic chemistry,2007,72(7):2538-2542.
APA	Zheng M,Li FF,Shi ZJ,Gao X,&Kadish KM.(2007).Electrosynthesis and characterization of 1,2-dibenzyl C-60: A revisit.journal of organic chemistry,72(7),2538-2542.
MLA	Zheng M,et al."Electrosynthesis and characterization of 1,2-dibenzyl C-60: A revisit".journal of organic chemistry 72.7(2007):2538-2542.