Synthesis, structure and electrochemical property of calixarene potassium polyoxometalates

	Synthesis, structure and electrochemical property of calixarene potassium polyoxometalates
	Liu JT ; Liu XW ; Fan SD ; Li DQ
刊名	chemical journal of chinese universities-chinese
	2007
卷号	28 期号:7 页码:1235-1239
关键词	MOLECULAR RECOGNITION ANION SENSORS BINDING COMPLEXES
ISSN号	0251-0790
通讯作者	liu jt
中文摘要	one inorganic-organic hybrid and two host-guest complexes were synthesized from calix[4] arene tetra acetic ether derivative( c60h80o12, l) and potassium polyoxometalates. the structures of the complexes were characterized with the elemental analysis, ir, tg-dta and x-crystallographic. x-ray crystallographic studies reveal the formation of an ionic crystal, which contains a calix-cluster and calix-cluster-calix line array, and belongs to a typical inorganic-organic hybrid ( complex 1) or has a host-guest structure ( complex 2 and 3). the results of cyclic voltammograms at different scanning rates showed that the anode peak current of complex 1 was proportional to the square root of the scanning rate and the charge transfer process was controlled by pervasion. the anode peak current of complexes 2 and 3 was proportional to the scanning rate and the charge transfer process was controlled by the surface. the results suggest that there are consanguineous relationship between the anode reaction and the structure.
收录类别	SCI
语种	中文
WOS记录号	WOS:000248202500008
公开日期	2010-07-13
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/14371]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Liu JT,Liu XW,Fan SD,et al. Synthesis, structure and electrochemical property of calixarene potassium polyoxometalates[J]. chemical journal of chinese universities-chinese,2007,28(7):1235-1239.
APA	Liu JT,Liu XW,Fan SD,&Li DQ.(2007).Synthesis, structure and electrochemical property of calixarene potassium polyoxometalates.chemical journal of chinese universities-chinese,28(7),1235-1239.
MLA	Liu JT,et al."Synthesis, structure and electrochemical property of calixarene potassium polyoxometalates".chemical journal of chinese universities-chinese 28.7(2007):1235-1239.