Synthesis, structure and electrochemical property of calixarene potassium polyoxometalates | |
Liu JT ; Liu XW ; Fan SD ; Li DQ | |
刊名 | chemical journal of chinese universities-chinese
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2007 | |
卷号 | 28期号:7页码:1235-1239 |
关键词 | MOLECULAR RECOGNITION ANION SENSORS BINDING COMPLEXES |
ISSN号 | 0251-0790 |
通讯作者 | liu jt |
中文摘要 | one inorganic-organic hybrid and two host-guest complexes were synthesized from calix[4] arene tetra acetic ether derivative( c60h80o12, l) and potassium polyoxometalates. the structures of the complexes were characterized with the elemental analysis, ir, tg-dta and x-crystallographic. x-ray crystallographic studies reveal the formation of an ionic crystal, which contains a calix-cluster and calix-cluster-calix line array, and belongs to a typical inorganic-organic hybrid ( complex 1) or has a host-guest structure ( complex 2 and 3). the results of cyclic voltammograms at different scanning rates showed that the anode peak current of complex 1 was proportional to the square root of the scanning rate and the charge transfer process was controlled by pervasion. the anode peak current of complexes 2 and 3 was proportional to the scanning rate and the charge transfer process was controlled by the surface. the results suggest that there are consanguineous relationship between the anode reaction and the structure. |
收录类别 | SCI |
语种 | 中文 |
WOS记录号 | WOS:000248202500008 |
公开日期 | 2010-07-13 |
内容类型 | 期刊论文 |
源URL | [http://ir.ciac.jl.cn/handle/322003/14371] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Liu JT,Liu XW,Fan SD,et al. Synthesis, structure and electrochemical property of calixarene potassium polyoxometalates[J]. chemical journal of chinese universities-chinese,2007,28(7):1235-1239. |
APA | Liu JT,Liu XW,Fan SD,&Li DQ.(2007).Synthesis, structure and electrochemical property of calixarene potassium polyoxometalates.chemical journal of chinese universities-chinese,28(7),1235-1239. |
MLA | Liu JT,et al."Synthesis, structure and electrochemical property of calixarene potassium polyoxometalates".chemical journal of chinese universities-chinese 28.7(2007):1235-1239. |
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