An investigation on the dispersion of montmorillonite (MMT) primary particles in PP matrix
Shi D ; Yu W ; Li RKY ; Ke Z ; Yin J
刊名european polymer journal
2007
卷号43期号:8页码:3250-3257
关键词POLYMER MELT INTERCALATION POLYPROPYLENE-CLAY HYBRIDS MODIFIED LAYERED SILICATES IN-SITU POLYMERIZATION NANOCOMPOSITE STRUCTURE MECHANICAL-PROPERTIES MALEIC-ANHYDRIDE STRATEGIES BEHAVIOR MODEL
ISSN号0014-3057
通讯作者li rky
中文摘要a novel path of preparing pp/o-mmt nanocomposites, which pay attention to the breaking up of mmt original agglomerates and dispersing of its primary particles, rather than the intercalation or exfoliation degree of o-mmt, was reported. the method of predispersing the o-mmt particles into a polar poly(vinyl alcohol) (pva) matrix and then melt blending the pre-treated pva/o-mmt hybrids with pp was studied. 3-isopropenyl-alpha,alpha-dimethylbenzene-isocyanate (tmi) was used as a modifier of pva to improve the compatibility between pva and pp matrix. pre-disperse o-mmt with tmi modified pva was proved to be an effective way to get a composite with fine o-mmt particles dispersion. but the method, which is pre-dispersing o-mmt with non modified pva and then using tmi to modify such pva/o-mmt hybrid, would largely reduce the reaction degree between tmi and pva because of the relatively lower reaction temperature. although the latter method also can obtain finer dispersion composites than that with using pp-g-mah as compatibilizer, the relatively higher degradation degree of pp matrix in this method will limit the use of this nanocomposite.
收录类别SCI
语种英语
WOS记录号WOS:000249446700015
公开日期2010-07-13
内容类型期刊论文
源URL[http://ir.ciac.jl.cn/handle/322003/14229]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
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Shi D,Yu W,Li RKY,et al. An investigation on the dispersion of montmorillonite (MMT) primary particles in PP matrix[J]. european polymer journal,2007,43(8):3250-3257.
APA Shi D,Yu W,Li RKY,Ke Z,&Yin J.(2007).An investigation on the dispersion of montmorillonite (MMT) primary particles in PP matrix.european polymer journal,43(8),3250-3257.
MLA Shi D,et al."An investigation on the dispersion of montmorillonite (MMT) primary particles in PP matrix".european polymer journal 43.8(2007):3250-3257.
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