Catalysts, Process Optimization, and Kinetics for the Production of Methyl Acrylate over Vanadium Phosphorus Oxide Catalysts | |
Guo, Xinpeng1,2; Yang, Dan1; Zuo, Cuncun1; Peng, Zhijian2; Li, Chunshan1; Zhang, Suojiang1 | |
刊名 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
![]() |
2017-05-24 | |
卷号 | 56期号:20页码:5860-5871 |
ISSN号 | 0888-5885 |
DOI | 10.1021/acs.iecr.7b01212 |
文献子类 | Article |
英文摘要 | Vanadium phosphorus oxide (VPO) catalysts were developed for the aldol condensation of methyl acetate (MeOAC) with formaldehyde (HCHO) to methyl acrylate (MA). The influence of P/V ratio on catalytic activity and selectivity was revealed and optimized with a fixed bed reactor. The controllable preparation of VPO catalyst was reached, and the influence of carrier gas on the resistance of carbon deposition was also systematically investigated. Response surface methodology (RSM) with three independent variables of molar ratio of MeOAC to HCHO, space velocity, and reaction temperature was employed to optimize MA yield with VPO catalysts. The high value of R-squared presented a reasonable correlation of regression model to the experimental data. Lastly, the kinetics of aldol condensation to produce MA over VPO catalyst was studied. |
WOS关键词 | Response-surface Methodology ; N-butane Oxidation ; Phase Aldol Condensation ; P-o Catalysts ; Vpo Catalysts ; Acetic-acid ; Bifunctional Catalyst ; Phosphate Catalysts ; Selective Oxidation ; Biodiesel Synthesis |
WOS研究方向 | Engineering |
语种 | 英语 |
WOS记录号 | WOS:000402498900010 |
资助机构 | National Science Fund for Excellent Young Scholars(21422607) ; National key R D program(2016YFB0601303) ; Key Research Program of Frontier Sciences, CAS(QYZDB-SSW-SLH022) |
内容类型 | 期刊论文 |
源URL | [http://ir.ipe.ac.cn/handle/122111/22652] ![]() |
专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Natl Key Lab Clean & Efficient Coking Technol, Beijing Key Lab Ion Liquids Clean Proc,State Key, Beijing 100190, Peoples R China 2.China Univ Geosci, Sch Engn & Technol, Beijing 100083, Peoples R China |
推荐引用方式 GB/T 7714 | Guo, Xinpeng,Yang, Dan,Zuo, Cuncun,et al. Catalysts, Process Optimization, and Kinetics for the Production of Methyl Acrylate over Vanadium Phosphorus Oxide Catalysts[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2017,56(20):5860-5871. |
APA | Guo, Xinpeng,Yang, Dan,Zuo, Cuncun,Peng, Zhijian,Li, Chunshan,&Zhang, Suojiang.(2017).Catalysts, Process Optimization, and Kinetics for the Production of Methyl Acrylate over Vanadium Phosphorus Oxide Catalysts.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,56(20),5860-5871. |
MLA | Guo, Xinpeng,et al."Catalysts, Process Optimization, and Kinetics for the Production of Methyl Acrylate over Vanadium Phosphorus Oxide Catalysts".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 56.20(2017):5860-5871. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论